Open Access

Molecules

, том 26 , издание 24 , страницы 7539

Novel Bispidine-Monoterpene Conjugates—Synthesis and Application as Ligands for the Catalytic Ethylation of Chalcones

Тип публикации: Journal Article

Дата публикации: 2021-12-13

MDPI

Molecules

SCImago Q1

WOS Q2

БС1

SJR: 0.915

CiteScore: 10.3

Impact factor: 4.6

ISSN: 14203049

DOI: 10.3390/molecules26247539

Скопировать DOI

PubMed ID: 34946622

Organic Chemistry

Drug Discovery

Physical and Theoretical Chemistry

Pharmaceutical Science

Molecular Medicine

Analytical Chemistry

Chemistry (miscellaneous)

Краткое описание

A number of new chiral bispidines containing monoterpenoid fragments have been obtained. The bispidines were studied as ligands for Ni-catalyzed addition of diethylzinc to chalcones. The conditions for chromatographic analysis by HPLC-UV were developed, in which the peaks of the enantiomers of all synthesized chiral products were separated, which made it possible to determine the enantiomeric excess of the resulting mixture. It was demonstrated that bispidine-monoterpenoid conjugates can be used as the ligands for diethylzinc addition to chalcone C=C double bond but not as inducers of chirality. Besides products of ethylation, formation of products of formal hydrogenation of the chalcone C=C double bond was observed in all cases. Note, that this formation of hydrogenation products in significant amounts in the presence of such catalytic systems was found for the first time. A tentative scheme explaining the formation of all products was proposed.

Для доступа к списку цитирований публикации необходимо авторизоваться.

Войти с ORCID

Для доступа к списку профилей, цитирующих публикацию, необходимо авторизоваться.

Войти с ORCID

Топ-30

Журналы

	1 2 3
Russian Chemical Bulletin	Russian Chemical Bulletin, 3, 20% Russian Chemical Bulletin 3 публикации, 20%
Molecules	Molecules, 2, 13.33% Molecules 2 публикации, 13.33%
Russian Journal of Organic Chemistry	Russian Journal of Organic Chemistry, 2, 13.33% Russian Journal of Organic Chemistry 2 публикации, 13.33%
Mendeleev Communications	Mendeleev Communications, 2, 13.33% Mendeleev Communications 2 публикации, 13.33%
Журнал органической химии	Журнал органической химии, 2, 13.33% Журнал органической химии 2 публикации, 13.33%
Russian Journal of General Chemistry	Russian Journal of General Chemistry, 1, 6.67% Russian Journal of General Chemistry 1 публикация, 6.67%
Chemistry	Chemistry, 1, 6.67% Chemistry 1 публикация, 6.67%
Chemical Record	Chemical Record, 1, 6.67% Chemical Record 1 публикация, 6.67%
Medicinal Chemistry Research	Medicinal Chemistry Research, 1, 6.67% Medicinal Chemistry Research 1 публикация, 6.67%
	1 2 3

Издатели

	1 2 3 4
Springer Nature	Springer Nature, 4, 26.67% Springer Nature 4 публикации, 26.67%
MDPI	MDPI, 3, 20% MDPI 3 публикации, 20%
Pleiades Publishing	Pleiades Publishing, 3, 20% Pleiades Publishing 3 публикации, 20%
OOO Zhurnal "Mendeleevskie Soobshcheniya"	OOO Zhurnal "Mendeleevskie Soobshcheniya", 2, 13.33% OOO Zhurnal "Mendeleevskie Soobshcheniya" 2 публикации, 13.33%
Wiley	Wiley, 1, 6.67% Wiley 1 публикация, 6.67%
Akademizdatcenter Nauka	Akademizdatcenter Nauka, 1, 6.67% Akademizdatcenter Nauka 1 публикация, 6.67%
The Russian Academy of Sciences	The Russian Academy of Sciences, 1, 6.67% The Russian Academy of Sciences 1 публикация, 6.67%
	1 2 3 4

Мы не учитываем публикации, у которых нет DOI.
Статистика публикаций обновляется еженедельно.

Вы ученый?

Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.

Войти с ORCID

PDF

Метрики

Цитировать

ГОСТ |

Цитировать

ГОСТ Скопировать

Suslov E. et al. Novel Bispidine-Monoterpene Conjugates—Synthesis and Application as Ligands for the Catalytic Ethylation of Chalcones // Molecules. 2021. Vol. 26. No. 24. p. 7539.

ГОСТ со всеми авторами (до 50) Скопировать

Suslov E., Ponomarev K. Y., Patrusheva O. S., Kuranov S. O., Okhina A. A., Rogachev A., Munkuev A. A., Ottenbacher R. V., Dalinger A. I., Kalinin M. A., Vatsadze S. Z., Volcho K. P., Salakhutdinov N. F. Novel Bispidine-Monoterpene Conjugates—Synthesis and Application as Ligands for the Catalytic Ethylation of Chalcones // Molecules. 2021. Vol. 26. No. 24. p. 7539.

RIS |

Цитировать

RIS Скопировать

TY - JOUR

DO - 10.3390/molecules26247539

UR - https://www.mdpi.com/1420-3049/26/24/7539

TI - Novel Bispidine-Monoterpene Conjugates—Synthesis and Application as Ligands for the Catalytic Ethylation of Chalcones

T2 - Molecules

AU - Suslov, E.V.

AU - Ponomarev, Konstantin Y

AU - Patrusheva, Oxana S

AU - Kuranov, Sergey O

AU - Okhina, Alina A

AU - Rogachev, Artem

AU - Munkuev, Aldar A

AU - Ottenbacher, Roman V

AU - Dalinger, Alexander I

AU - Kalinin, Mikhail A

AU - Vatsadze, Sergey Z

AU - Volcho, Konstantin P.

AU - Salakhutdinov, Nariman F.

PY - 2021

DA - 2021/12/13

PB - MDPI

SP - 7539

IS - 24

VL - 26

PMID - 34946622

SN - 1420-3049

ER -

BibTex |

Цитировать

BibTex (до 50 авторов) Скопировать

@article{2021_Suslov,

author = {E.V. Suslov and Konstantin Y Ponomarev and Oxana S Patrusheva and Sergey O Kuranov and Alina A Okhina and Artem Rogachev and Aldar A Munkuev and Roman V Ottenbacher and Alexander I Dalinger and Mikhail A Kalinin and Sergey Z Vatsadze and Konstantin P. Volcho and Nariman F. Salakhutdinov},

title = {Novel Bispidine-Monoterpene Conjugates—Synthesis and Application as Ligands for the Catalytic Ethylation of Chalcones},

journal = {Molecules},

year = {2021},

volume = {26},

publisher = {MDPI},

month = {dec},

url = {https://www.mdpi.com/1420-3049/26/24/7539},

number = {24},

pages = {7539},

doi = {10.3390/molecules26247539}

}

MLA

Цитировать

MLA Скопировать

Suslov, E.V., et al. “Novel Bispidine-Monoterpene Conjugates—Synthesis and Application as Ligands for the Catalytic Ethylation of Chalcones.” Molecules, vol. 26, no. 24, Dec. 2021, p. 7539. https://www.mdpi.com/1420-3049/26/24/7539.

Издатель

MDPI

Журнал

Molecules

SCImago Q1

WOS Q2

БС1

SJR

0.915

CiteScore

10.3

Impact factor