Open Access
Catalytic Approaches to Multicomponent Reactions: A Critical Review and Perspectives on the Roles of Catalysis
Publication type: Journal Article
Publication date: 2021-12-27
PubMed ID:
35011363
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
In this review, we comprehensively describe catalyzed multicomponent reactions (MCRs) and the multiple roles of catalysis combined with key parameters to perform these transformations. Besides improving yields and shortening reaction times, catalysis is vital to achieving greener protocols and to furthering the MCR field of research. Considering that MCRs typically have two or more possible reaction pathways to explain the transformation, catalysis is essential for selecting a reaction route and avoiding byproduct formation. Key parameters, such as temperature, catalyst amounts and reagent quantities, were analyzed. Solvent effects, which are likely the most neglected topic in MCRs, as well as their combined roles with catalysis, are critically discussed. Stereocontrolled MCRs, rarely observed without the presence of a catalytic system, are also presented and discussed in this review. Perspectives on the use of catalytic systems for improved and greener MCRs are finally presented.
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Metrics
84
Total citations:
84
Citations from 2024:
55
(65.48%)
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GOST
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Neto B. A. et al. Catalytic Approaches to Multicomponent Reactions: A Critical Review and Perspectives on the Roles of Catalysis // Molecules. 2021. Vol. 27. No. 1. p. 132.
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Neto B. A., Rocha R. O., Rodrigues M. O. Catalytic Approaches to Multicomponent Reactions: A Critical Review and Perspectives on the Roles of Catalysis // Molecules. 2021. Vol. 27. No. 1. p. 132.
Cite this
RIS
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TY - JOUR
DO - 10.3390/molecules27010132
UR - https://doi.org/10.3390/molecules27010132
TI - Catalytic Approaches to Multicomponent Reactions: A Critical Review and Perspectives on the Roles of Catalysis
T2 - Molecules
AU - Neto, Brenno A.D.
AU - Rocha, Rafael O
AU - Rodrigues, Marcelo O
PY - 2021
DA - 2021/12/27
PB - MDPI
SP - 132
IS - 1
VL - 27
PMID - 35011363
SN - 1420-3049
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Neto,
author = {Brenno A.D. Neto and Rafael O Rocha and Marcelo O Rodrigues},
title = {Catalytic Approaches to Multicomponent Reactions: A Critical Review and Perspectives on the Roles of Catalysis},
journal = {Molecules},
year = {2021},
volume = {27},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/molecules27010132},
number = {1},
pages = {132},
doi = {10.3390/molecules27010132}
}
Cite this
MLA
Copy
Neto, Brenno A.D., et al. “Catalytic Approaches to Multicomponent Reactions: A Critical Review and Perspectives on the Roles of Catalysis.” Molecules, vol. 27, no. 1, Dec. 2021, p. 132. https://doi.org/10.3390/molecules27010132.