Open Access
Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds
Anastasiya Shesterkina
1, 2
,
Kseniia Vikanova
2
,
Anna Strekalova
1, 2
,
Elena Shuvalova
2
,
Gennady Kapustin
2
,
Tapio Salmi
3
Publication type: Journal Article
Publication date: 2022-02-01
PubMed ID:
35164251
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
For the first time, the new microwave-assisted method for the synthesis of copper phyllosilicates on a commercial SiO2 carrier was developed. The application of microwave synthesis allowed to decrease the synthesis time from 9 to 6 h compared to the traditional DPU method of preparing chrysocolla. The synthesized catalysts were studied by N2 adsorption, TEM and XRD methods. Catalysts prepared by microwave method are highly effective in the selective hydrogenation of the С≡С bond in 1,4-butynediol to 1,4-butenediol and 2-phenylethinylaniline with a selectivity of 96.5% and 100% at full conversion for 2 and 0.5 h of the reaction, respectively.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Molecules
2 publications, 20%
|
|
|
International Journal of Molecular Sciences
1 publication, 10%
|
|
|
ChemCatChem
1 publication, 10%
|
|
|
Molecular Catalysis
1 publication, 10%
|
|
|
Applied Clay Science
1 publication, 10%
|
|
|
Mendeleev Communications
1 publication, 10%
|
|
|
ACS Sustainable Chemistry and Engineering
1 publication, 10%
|
|
|
Catalysts
1 publication, 10%
|
|
|
Chemistry of Materials
1 publication, 10%
|
|
|
1
2
|
Publishers
|
1
2
3
4
|
|
|
MDPI
4 publications, 40%
|
|
|
Elsevier
2 publications, 20%
|
|
|
American Chemical Society (ACS)
2 publications, 20%
|
|
|
Wiley
1 publication, 10%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 10%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
10
Total citations:
10
Citations from 2025:
3
(30%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Shesterkina A. et al. Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds // Molecules. 2022. Vol. 27. No. 3. p. 988.
GOST all authors (up to 50)
Copy
Shesterkina A., Vikanova K., Kostyukhin E. M., Strekalova A., Shuvalova E., Kapustin G., Salmi T. Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds // Molecules. 2022. Vol. 27. No. 3. p. 988.
Cite this
RIS
Copy
TY - JOUR
DO - 10.3390/molecules27030988
UR - https://doi.org/10.3390/molecules27030988
TI - Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds
T2 - Molecules
AU - Shesterkina, Anastasiya
AU - Vikanova, Kseniia
AU - Kostyukhin, Egor M
AU - Strekalova, Anna
AU - Shuvalova, Elena
AU - Kapustin, Gennady
AU - Salmi, Tapio
PY - 2022
DA - 2022/02/01
PB - MDPI
SP - 988
IS - 3
VL - 27
PMID - 35164251
SN - 1420-3049
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Shesterkina,
author = {Anastasiya Shesterkina and Kseniia Vikanova and Egor M Kostyukhin and Anna Strekalova and Elena Shuvalova and Gennady Kapustin and Tapio Salmi},
title = {Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds},
journal = {Molecules},
year = {2022},
volume = {27},
publisher = {MDPI},
month = {feb},
url = {https://doi.org/10.3390/molecules27030988},
number = {3},
pages = {988},
doi = {10.3390/molecules27030988}
}
Cite this
MLA
Copy
Shesterkina, Anastasiya, et al. “Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds.” Molecules, vol. 27, no. 3, Feb. 2022, p. 988. https://doi.org/10.3390/molecules27030988.