Open Access
Diels–Alder Cycloaddition Reactions in Sustainable Media
Publication type: Journal Article
Publication date: 2022-02-15
PubMed ID:
35209094
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
Diels–Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity. In this review, an insight into the most relevant advances on sustainable Diels–Alder reactions since 2010 is provided. Various environmentally benign solvent systems are discussed, namely bio-based derived solvents (such as glycerol and gluconic acid), polyethylene glycol, deep eutectic solvents, supercritical carbon dioxide, water and water-based aqueous systems. Issues such as method’s scope, efficiency, selectivity and reaction mechanism, as well as sustainability, advantages and limitations of these reaction media, are addressed.
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Metrics
22
Total citations:
22
Citations from 2024:
15
(68%)
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BibTex |
MLA
Cite this
GOST
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Soares M. I. L., Cardoso A. L., Pinho e Melo T. Diels–Alder Cycloaddition Reactions in Sustainable Media // Molecules. 2022. Vol. 27. No. 4. p. 1304.
GOST all authors (up to 50)
Copy
Soares M. I. L., Cardoso A. L., Pinho e Melo T. Diels–Alder Cycloaddition Reactions in Sustainable Media // Molecules. 2022. Vol. 27. No. 4. p. 1304.
Cite this
RIS
Copy
TY - JOUR
DO - 10.3390/molecules27041304
UR - https://doi.org/10.3390/molecules27041304
TI - Diels–Alder Cycloaddition Reactions in Sustainable Media
T2 - Molecules
AU - Soares, M. I. L.
AU - Cardoso, Ana L.
AU - Pinho e Melo, Teresa
PY - 2022
DA - 2022/02/15
PB - MDPI
SP - 1304
IS - 4
VL - 27
PMID - 35209094
SN - 1420-3049
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Soares,
author = {M. I. L. Soares and Ana L. Cardoso and Teresa Pinho e Melo},
title = {Diels–Alder Cycloaddition Reactions in Sustainable Media},
journal = {Molecules},
year = {2022},
volume = {27},
publisher = {MDPI},
month = {feb},
url = {https://doi.org/10.3390/molecules27041304},
number = {4},
pages = {1304},
doi = {10.3390/molecules27041304}
}
Cite this
MLA
Copy
Soares, M. I. L., et al. “Diels–Alder Cycloaddition Reactions in Sustainable Media.” Molecules, vol. 27, no. 4, Feb. 2022, p. 1304. https://doi.org/10.3390/molecules27041304.