Open Access
Molecules, volume 27, issue 7, pages 2147
Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents
Publication type: Journal Article
Publication date: 2022-03-26
PubMed ID:
35408545
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
Derivatives of main group elements containing element–element bonds are characterized by unique properties due to σ-conjugation, which is an attractive subject for investigation. A novel series of digermanes, Ar3Ge-Ge(SiMe3)3, containing aryl (Ar = p-C6H4Me (1), p-C6H4F (2), C6F5 (3)) and trimethylsilyl substituents, was synthesized by the reaction of germyl potassium salt, [(Me3Si)3GeK*THF], with triarylchlorogermanes, Ar3GeCl. The optical and electronic properties of such substituted oligoorganogermanes were investigated spectroscopically by UV/vis absorption spectroscopy and theoretically by DFT calculations. The molecular structures of compounds 1 and 2 were studied by XRD analysis. Conjugation between all structural fragments (Ge-Ge, Ge-Si, Ge-Ar, where Ar is an electron-donating or withdrawing group) was found to affect the properties.
Citations by journals
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1
2
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International Journal of Molecular Sciences
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International Journal of Molecular Sciences
2 publications, 66.67%
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Chemistry - An Asian Journal
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Chemistry - An Asian Journal
1 publication, 33.33%
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1
2
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Citations by publishers
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1
2
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 66.67%
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Wiley
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Wiley
1 publication, 33.33%
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1
2
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Zaitsev K. V. et al. Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents // Molecules. 2022. Vol. 27. No. 7. p. 2147.
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Zaitsev K. V., Poleshchuk O. Kh., Churakov A. V. Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents // Molecules. 2022. Vol. 27. No. 7. p. 2147.
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TY - JOUR
DO - 10.3390/molecules27072147
UR - https://doi.org/10.3390%2Fmolecules27072147
TI - Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents
T2 - Molecules
AU - Poleshchuk, Oleg Kh
AU - Zaitsev, K V
AU - Churakov, Andrei V.
PY - 2022
DA - 2022/03/26 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 2147
IS - 7
VL - 27
PMID - 35408545
SN - 1420-3049
ER -
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@article{2022_Zaitsev,
author = {Oleg Kh Poleshchuk and K V Zaitsev and Andrei V. Churakov},
title = {Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents},
journal = {Molecules},
year = {2022},
volume = {27},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {mar},
url = {https://doi.org/10.3390%2Fmolecules27072147},
number = {7},
pages = {2147},
doi = {10.3390/molecules27072147}
}
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Zaitsev, K. V., et al. “Oligoorganogermanes: Interplay between Aryl and Trimethylsilyl Substituents.” Molecules, vol. 27, no. 7, Mar. 2022, p. 2147. https://doi.org/10.3390%2Fmolecules27072147.
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