Open Access
First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III)
Yuri A. Ustynyuk
1
,
Pavel S. Lemport
1
,
Vitaly A. Roznyatovsky
1
,
Alexey O Gudovannyy
1
,
Petr I Matveev
1
,
E K Khult
2
,
Igor P. Gloriozov
1
,
Anton S Pozdeev
1
,
Valentine S Petrov
1
,
Nane A Avagyan
1
,
Alexander S Aldoshin
1
,
Publication type: Journal Article
Publication date: 2022-05-12
PubMed ID:
35630590
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
The first examples of 1,10-phenanthroline-2,9-diamides bearing CF3-groups on the side amide substituents were synthesized. Due to stereoisomerism and amide rotation, such complexes have complicated behavior in solutions. Using advanced NMR techniques and X-ray analysis, their structures were completely elucidated. The possibility of the formation of complex compounds with lanthanoids nitrates was shown, and the constants of their stability are quantified. The results obtained are explained in terms of quantum-chemical calculations.
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23
Total citations:
23
Citations from 2024:
13
(56.52%)
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GOST
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Ustynyuk Y. A. et al. First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III) // Molecules. 2022. Vol. 27. No. 10. p. 3114.
GOST all authors (up to 50)
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Ustynyuk Y. A., Lemport P. S., Roznyatovsky V. A., Lyssenko K. A., Gudovannyy A. O., Matveev P. I., Khult E. K., Evsiunina M. V., Petrov V. G., Gloriozov I. P., Pozdeev A. S., Petrov V. S., Avagyan N. A., Aldoshin A. S., Kalmykov S. N., Nenajdenko V. G. First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III) // Molecules. 2022. Vol. 27. No. 10. p. 3114.
Cite this
RIS
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TY - JOUR
DO - 10.3390/molecules27103114
UR - https://www.mdpi.com/1420-3049/27/10/3114
TI - First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III)
T2 - Molecules
AU - Ustynyuk, Yuri A.
AU - Lemport, Pavel S.
AU - Roznyatovsky, Vitaly A.
AU - Lyssenko, Konstantin A.
AU - Gudovannyy, Alexey O
AU - Matveev, Petr I
AU - Khult, E K
AU - Evsiunina, Mariia V
AU - Petrov, Vladimir G
AU - Gloriozov, Igor P.
AU - Pozdeev, Anton S
AU - Petrov, Valentine S
AU - Avagyan, Nane A
AU - Aldoshin, Alexander S
AU - Kalmykov, Stepan N.
AU - Nenajdenko, Valentine G.
PY - 2022
DA - 2022/05/12
PB - MDPI
SP - 3114
IS - 10
VL - 27
PMID - 35630590
SN - 1420-3049
ER -
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BibTex (up to 50 authors)
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@article{2022_Ustynyuk,
author = {Yuri A. Ustynyuk and Pavel S. Lemport and Vitaly A. Roznyatovsky and Konstantin A. Lyssenko and Alexey O Gudovannyy and Petr I Matveev and E K Khult and Mariia V Evsiunina and Vladimir G Petrov and Igor P. Gloriozov and Anton S Pozdeev and Valentine S Petrov and Nane A Avagyan and Alexander S Aldoshin and Stepan N. Kalmykov and Valentine G. Nenajdenko},
title = {First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III)},
journal = {Molecules},
year = {2022},
volume = {27},
publisher = {MDPI},
month = {may},
url = {https://www.mdpi.com/1420-3049/27/10/3114},
number = {10},
pages = {3114},
doi = {10.3390/molecules27103114}
}
Cite this
MLA
Copy
Ustynyuk, Yuri A., et al. “First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III).” Molecules, vol. 27, no. 10, May. 2022, p. 3114. https://www.mdpi.com/1420-3049/27/10/3114.