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volume 27 issue 16 pages 5093

High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine

Ludmila G. Lavrenova 1
Olga G. Shakirova 1, 2
Alexsei Ya Tikhonov 3
Irina A Oskina 3
Sergey A. Petrov 4
Nikolay T. Kuznetsov 5
Publication typeJournal Article
Publication date2022-08-10
scimago Q1
wos Q2
SJR0.865
CiteScore8.6
Impact factor4.6
ISSN14203049
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract

Novel iron(II) coordination compounds containing a ligand 2,6-bis(1H-imidazol-2-yl)pyridine (L), having such a composition as [FeL2]SO4·0.5H2O, [FeL2]Br2·H2O, [FeL2](ReO4)2, [FeL2]B10H10∙H2O, [FeL2]B12H12∙1.5H2O had been synthesized and studied using UV-Vis (diffuse reflectance), infrared, extended X-ray absorption fine structure (EXAFS), and Mössbauer spectroscopy methods, as well as X-ray diffraction and static magnetic susceptibility methods. The analysis of the μeff(T) dependence in the temperature range of 80–600 K have shown that all the obtained complexes exhibit a high-temperature spin crossover 1A1 ↔ 5T2.

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GOST Copy
Lavrenova L. G. et al. High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine // Molecules. 2022. Vol. 27. No. 16. p. 5093.
GOST all authors (up to 50) Copy
Lavrenova L. G., Shakirova O. G., Korotaev E. V., Trubina S. V., Tikhonov A. Ya., Oskina I. A., Petrov S. A., Zhizhin K. Y., Kuznetsov N. T. High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine // Molecules. 2022. Vol. 27. No. 16. p. 5093.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.3390/molecules27165093
UR - https://www.mdpi.com/1420-3049/27/16/5093
TI - High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine
T2 - Molecules
AU - Lavrenova, Ludmila G.
AU - Shakirova, Olga G.
AU - Korotaev, Evgeniy V
AU - Trubina, Svetlana V
AU - Tikhonov, Alexsei Ya
AU - Oskina, Irina A
AU - Petrov, Sergey A.
AU - Zhizhin, Konstantin Yu.
AU - Kuznetsov, Nikolay T.
PY - 2022
DA - 2022/08/10
PB - MDPI
SP - 5093
IS - 16
VL - 27
PMID - 36014332
SN - 1420-3049
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Lavrenova,
author = {Ludmila G. Lavrenova and Olga G. Shakirova and Evgeniy V Korotaev and Svetlana V Trubina and Alexsei Ya Tikhonov and Irina A Oskina and Sergey A. Petrov and Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov},
title = {High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine},
journal = {Molecules},
year = {2022},
volume = {27},
publisher = {MDPI},
month = {aug},
url = {https://www.mdpi.com/1420-3049/27/16/5093},
number = {16},
pages = {5093},
doi = {10.3390/molecules27165093}
}
MLA
Cite this
MLA Copy
Lavrenova, Ludmila G., et al. “High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1H-imidazol-2-yl)pyridine.” Molecules, vol. 27, no. 16, Aug. 2022, p. 5093. https://www.mdpi.com/1420-3049/27/16/5093.