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First Example of Cage P4N4-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu2I Fragments
Publication type: Journal Article
Publication date: 2023-01-09
PubMed ID:
36677737
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Abstract
In this study, 28-membered macrocyclic 1,5(1,5)-di(1,5-diaza-3,7-diphosphacyclooctana)-2,4,6,8(1,4)-tetrabenzenacyclooctaphane were synthesized by condensation of pyridinephosphine, paraformaldehyde, and primary diamines (bis(4-aminophenyl)methane or –sulfide. The first representatives of binuclear copper(I) complexes of P,N-containing cyclophanes with two 1,5-diaza-3,7-diphosphacyclooctane rings incorporated into a macrocyclic core and intracavity location of unusual, developed angle Сu2I moiety were obtained. The structure of one complex was established by X-ray diffraction analysis. The complexation led to a slight distortion of the cyclophane conformations.
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Balueva A. S. et al. First Example of Cage P4N4-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu2I Fragments // Molecules. 2023. Vol. 28. No. 2. p. 680.
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Balueva A. S., Nikolaeva Y. A., Musina E., Litvinov I. A., Karasik A. A. First Example of Cage P4N4-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu2I Fragments // Molecules. 2023. Vol. 28. No. 2. p. 680.
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TY - JOUR
DO - 10.3390/molecules28020680
UR - https://doi.org/10.3390/molecules28020680
TI - First Example of Cage P4N4-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu2I Fragments
T2 - Molecules
AU - Balueva, Anna S
AU - Nikolaeva, Yulia A
AU - Musina, Elvira
AU - Litvinov, Igor A
AU - Karasik, Andrey A
PY - 2023
DA - 2023/01/09
PB - MDPI
SP - 680
IS - 2
VL - 28
PMID - 36677737
SN - 1420-3049
ER -
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@article{2023_Balueva,
author = {Anna S Balueva and Yulia A Nikolaeva and Elvira Musina and Igor A Litvinov and Andrey A Karasik},
title = {First Example of Cage P4N4-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu2I Fragments},
journal = {Molecules},
year = {2023},
volume = {28},
publisher = {MDPI},
month = {jan},
url = {https://doi.org/10.3390/molecules28020680},
number = {2},
pages = {680},
doi = {10.3390/molecules28020680}
}
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MLA
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Balueva, Anna S., et al. “First Example of Cage P4N4-Macrocycle Copper Complexes with Intracavity Location of Unusual Cu2I Fragments.” Molecules, vol. 28, no. 2, Jan. 2023, p. 680. https://doi.org/10.3390/molecules28020680.
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