Open Access
Synthesis of CF3-Containing Spiro-[Indene-Proline] Derivatives via Rh(III)-Catalyzed C-H Activation/Annulation
Тип публикации: Journal Article
Дата публикации: 2023-11-27
PubMed ID:
38067539
Organic Chemistry
Drug Discovery
Physical and Theoretical Chemistry
Pharmaceutical Science
Molecular Medicine
Analytical Chemistry
Chemistry (miscellaneous)
Краткое описание
An efficient method of accessing new CF3-containing spiro-[indene-proline] derivatives has been developed based on a Cp*Rh(III)-catalyzed tandem C-H activation/[3+2]–annulation reaction of 5-aryl-2-(trifluoromethyl)-3,4-dihydro-2H-pyrrole-2-carboxylates with alkynes. An important feature of this spiro annulation process is the feasibility of dehydroproline moiety to act as a directing group in the selective activation of the aromatic C-H bond.
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Bubnova A. S. et al. Synthesis of CF3-Containing Spiro-[Indene-Proline] Derivatives via Rh(III)-Catalyzed C-H Activation/Annulation // Molecules. 2023. Vol. 28. No. 23. p. 7809.
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Bubnova A. S., Vorobyeva D. V., Godovikov I. A., Smol’yakov A. F., Osipov S. N. Synthesis of CF3-Containing Spiro-[Indene-Proline] Derivatives via Rh(III)-Catalyzed C-H Activation/Annulation // Molecules. 2023. Vol. 28. No. 23. p. 7809.
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TY - JOUR
DO - 10.3390/molecules28237809
UR - https://doi.org/10.3390/molecules28237809
TI - Synthesis of CF3-Containing Spiro-[Indene-Proline] Derivatives via Rh(III)-Catalyzed C-H Activation/Annulation
T2 - Molecules
AU - Bubnova, Alexandra S.
AU - Vorobyeva, Daria V
AU - Godovikov, Ivan A.
AU - Smol’yakov, Alexander F.
AU - Osipov, Sergey N.
PY - 2023
DA - 2023/11/27
PB - MDPI
SP - 7809
IS - 23
VL - 28
PMID - 38067539
SN - 1420-3049
ER -
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@article{2023_Bubnova,
author = {Alexandra S. Bubnova and Daria V Vorobyeva and Ivan A. Godovikov and Alexander F. Smol’yakov and Sergey N. Osipov},
title = {Synthesis of CF3-Containing Spiro-[Indene-Proline] Derivatives via Rh(III)-Catalyzed C-H Activation/Annulation},
journal = {Molecules},
year = {2023},
volume = {28},
publisher = {MDPI},
month = {nov},
url = {https://doi.org/10.3390/molecules28237809},
number = {23},
pages = {7809},
doi = {10.3390/molecules28237809}
}
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Bubnova, Alexandra S., et al. “Synthesis of CF3-Containing Spiro-[Indene-Proline] Derivatives via Rh(III)-Catalyzed C-H Activation/Annulation.” Molecules, vol. 28, no. 23, Nov. 2023, p. 7809. https://doi.org/10.3390/molecules28237809.
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