Open Access

Nanomaterials, volume 10, issue 8, pages 1606

Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review

M.S. Reddy ¹

Christian M. Julien ²

Alain Mauger ²

Karim Zaghib ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Centre of Excellence in Transportation Electrification and Energy Storage (CETEES), Institute of Research Hydro-Québec, 1806, Lionel-Boulet Blvd., Varennes, QC J3X 1S1, Canada |

Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie (IMPMC), Sorbonne Université, UMR-CNRS 7590, 4 place Jussieu, 75252 Paris, France |

Department of Mining and Materials Engineering, McGill University, Wong Building, 3610 University Street, Montreal, QC H3A OC5, Canada |

Publication type: Journal Article

Publication date: 2020-08-15

Multidisciplinary Digital Publishing Institute (MDPI)

Journal: Nanomaterials

Quartile SCImago

Quartile WOS

Impact factor: 5.3

ISSN: 20794991

DOI: 10.3390/nano10081606

Copy DOI

General Chemical Engineering

General Materials Science

Abstract

Energy storage materials are finding increasing applications in our daily lives, for devices such as mobile phones and electric vehicles. Current commercial batteries use flammable liquid electrolytes, which are unsafe, toxic, and environmentally unfriendly with low chemical stability. Recently, solid electrolytes have been extensively studied as alternative electrolytes to address these shortcomings. Herein, we report the early history, synthesis and characterization, mechanical properties, and Li+ ion transport mechanisms of inorganic sulfide and oxide electrolytes. Furthermore, we highlight the importance of the fabrication technology and experimental conditions, such as the effects of pressure and operating parameters, on the electrochemical performance of all-solid-state Li batteries. In particular, we emphasize promising electrolyte systems based on sulfides and argyrodites, such as LiPS5Cl and β-Li3PS4, oxide electrolytes, bare and doped Li7La3Zr2O12 garnet, NASICON-type structures, and perovskite electrolyte materials. Moreover, we discuss the present and future challenges that all-solid-state batteries face for large-scale industrial applications.

By date By citations

Top-30

Citations by journals

	1 2 3 4 5 6 7 8 9
Energy Storage Materials	Energy Storage Materials, 9, 4.52% Energy Storage Materials 9 publications, 4.52%
Journal of Power Sources	Journal of Power Sources, 8, 4.02% Journal of Power Sources 8 publications, 4.02%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 7, 3.52% Journal of the Electrochemical Society 7 publications, 3.52%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 6, 3.02% Journal of Materials Chemistry A 6 publications, 3.02%
ACS applied materials & interfaces	ACS applied materials & interfaces, 6, 3.02% ACS applied materials & interfaces 6 publications, 3.02%
Batteries	Batteries, 5, 2.51% Batteries 5 publications, 2.51%
Solid State Ionics	Solid State Ionics, 5, 2.51% Solid State Ionics 5 publications, 2.51%
Electrochimica Acta	Electrochimica Acta, 5, 2.51% Electrochimica Acta 5 publications, 2.51%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 5, 2.51% Journal of Alloys and Compounds 5 publications, 2.51%
Advanced Functional Materials	Advanced Functional Materials, 5, 2.51% Advanced Functional Materials 5 publications, 2.51%
Materials	Materials, 4, 2.01% Materials 4 publications, 2.01%
Ceramics International	Ceramics International, 4, 2.01% Ceramics International 4 publications, 2.01%
ACS Applied Energy Materials	ACS Applied Energy Materials, 4, 2.01% ACS Applied Energy Materials 4 publications, 2.01%
Chemistry of Materials	Chemistry of Materials, 4, 2.01% Chemistry of Materials 4 publications, 2.01%
Physical Review Materials	Physical Review Materials, 3, 1.51% Physical Review Materials 3 publications, 1.51%
Nanomaterials	Nanomaterials, 3, 1.51% Nanomaterials 3 publications, 1.51%
Journal of Solid State Chemistry	Journal of Solid State Chemistry, 3, 1.51% Journal of Solid State Chemistry 3 publications, 1.51%
Journal of the European Ceramic Society	Journal of the European Ceramic Society, 3, 1.51% Journal of the European Ceramic Society 3 publications, 1.51%
Advanced Energy and Sustainability Research	Advanced Energy and Sustainability Research, 3, 1.51% Advanced Energy and Sustainability Research 3 publications, 1.51%
Inorganic Chemistry	Inorganic Chemistry, 3, 1.51% Inorganic Chemistry 3 publications, 1.51%
Advanced Energy Materials	Advanced Energy Materials, 3, 1.51% Advanced Energy Materials 3 publications, 1.51%
Scientific Reports	Scientific Reports, 2, 1.01% Scientific Reports 2 publications, 1.01%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 2, 1.01% Journal of Solid State Electrochemistry 2 publications, 1.01%
Ionics	Ionics, 2, 1.01% Ionics 2 publications, 1.01%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 2, 1.01% Journal of Colloid and Interface Science 2 publications, 1.01%
Materials Chemistry and Physics	Materials Chemistry and Physics, 2, 1.01% Materials Chemistry and Physics 2 publications, 1.01%
ChemElectroChem	ChemElectroChem, 2, 1.01% ChemElectroChem 2 publications, 1.01%
ACS Materials Letters	ACS Materials Letters, 2, 1.01% ACS Materials Letters 2 publications, 1.01%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 2, 1.01% Materials Chemistry Frontiers 2 publications, 1.01%
	1 2 3 4 5 6 7 8 9

Citations by publishers

	10 20 30 40 50 60 70
Elsevier	Elsevier, 70, 35.18% Elsevier 70 publications, 35.18%
American Chemical Society (ACS)	American Chemical Society (ACS), 26, 13.07% American Chemical Society (ACS) 26 publications, 13.07%
Wiley	Wiley, 26, 13.07% Wiley 26 publications, 13.07%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 20, 10.05% Multidisciplinary Digital Publishing Institute (MDPI) 20 publications, 10.05%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 14, 7.04% Royal Society of Chemistry (RSC) 14 publications, 7.04%
Springer Nature	Springer Nature, 14, 7.04% Springer Nature 14 publications, 7.04%
The Electrochemical Society	The Electrochemical Society, 8, 4.02% The Electrochemical Society 8 publications, 4.02%
American Physical Society (APS)	American Physical Society (APS), 3, 1.51% American Physical Society (APS) 3 publications, 1.51%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 0.5% American Institute of Physics (AIP) 1 publication, 0.5%
Japan Institute of Metals and Materials	Japan Institute of Metals and Materials, 1, 0.5% Japan Institute of Metals and Materials 1 publication, 0.5%
Frontiers Media S.A.	Frontiers Media S.A., 1, 0.5% Frontiers Media S.A. 1 publication, 0.5%
Nonferrous Metals Society of China	Nonferrous Metals Society of China, 1, 0.5% Nonferrous Metals Society of China 1 publication, 0.5%
University of Science and Technology Beijing	University of Science and Technology Beijing, 1, 0.5% University of Science and Technology Beijing 1 publication, 0.5%
Tianjin Daxue/Tianjin University	Tianjin Daxue/Tianjin University, 1, 0.5% Tianjin Daxue/Tianjin University 1 publication, 0.5%
Chinese Society of Rare Earths	Chinese Society of Rare Earths, 1, 0.5% Chinese Society of Rare Earths 1 publication, 0.5%
Taylor & Francis	Taylor & Francis, 1, 0.5% Taylor & Francis 1 publication, 0.5%
Walter de Gruyter	Walter de Gruyter, 1, 0.5% Walter de Gruyter 1 publication, 0.5%
National Academy of Sciences of Ukraine - Institute of Semiconductor Physics	National Academy of Sciences of Ukraine - Institute of Semiconductor Physics, 1, 0.5% National Academy of Sciences of Ukraine - Institute of Semiconductor Physics 1 publication, 0.5%
Chinese Physical Society	Chinese Physical Society, 1, 0.5% Chinese Physical Society 1 publication, 0.5%
Ceramic Society of Japan	Ceramic Society of Japan, 1, 0.5% Ceramic Society of Japan 1 publication, 0.5%
IOP Publishing	IOP Publishing, 1, 0.5% IOP Publishing 1 publication, 0.5%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 0.5% American Association for the Advancement of Science (AAAS) 1 publication, 0.5%
Diponegoro university Indonesia - Center of Biomass and Renewable Energy (CBIORE)	Diponegoro university Indonesia - Center of Biomass and Renewable Energy (CBIORE), 1, 0.5% Diponegoro university Indonesia - Center of Biomass and Renewable Energy (CBIORE) 1 publication, 0.5%
OAE Publishing Inc.	OAE Publishing Inc., 1, 0.5% OAE Publishing Inc. 1 publication, 0.5%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 0.5% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 0.5%
	10 20 30 40 50 60 70

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

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Reddy M. et al. Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review // Nanomaterials. 2020. Vol. 10. No. 8. p. 1606.

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Reddy M., Julien C. M., Mauger A., Zaghib K. Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review // Nanomaterials. 2020. Vol. 10. No. 8. p. 1606.

RIS |

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RIS Copy

TY - JOUR

DO - 10.3390/nano10081606

UR - https://doi.org/10.3390/nano10081606

TI - Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review

T2 - Nanomaterials

AU - Mauger, Alain

AU - Zaghib, Karim

AU - Reddy, M.S.

AU - Julien, Christian M.

PY - 2020

DA - 2020/08/15 00:00:00

PB - Multidisciplinary Digital Publishing Institute (MDPI)

SP - 1606

IS - 8

VL - 10

SN - 2079-4991

ER -

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BibTex Copy

@article{2020_Reddy,

author = {Alain Mauger and Karim Zaghib and M.S. Reddy and Christian M. Julien},

title = {Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review},

journal = {Nanomaterials},

year = {2020},

volume = {10},

publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},

month = {aug},

url = {https://doi.org/10.3390/nano10081606},

number = {8},

pages = {1606},

doi = {10.3390/nano10081606}

}

MLA

Cite this

MLA Copy

Reddy, M.S., et al. “Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review.” Nanomaterials, vol. 10, no. 8, Aug. 2020, p. 1606. https://doi.org/10.3390/nano10081606.

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Publisher

Multidisciplinary Digital Publishing Institute (MDPI)

Journal

Nanomaterials

Quartile SCImago

Quartile WOS

Impact factor

5.3

ISSN

20794991 (Electronic)