Open Access
Nanomaterials, volume 12, issue 12, pages 2023
Improvement of the Interface between the Lithium Anode and a Garnet-Type Solid Electrolyte of Lithium Batteries Using an Aluminum-Nitride Layer
Publication type: Journal Article
Publication date: 2022-06-12
General Chemical Engineering
General Materials Science
Abstract
The next generation of all-solid-state batteries can feature battery safety that is unparalleled among conventional liquid batteries. The garnet-type solid-state electrolyte Li7La3Zr2O12 (LLZO), in particular, is widely studied because of its high Li-ion conductivity and stability in air. However, the poor interface-contact between Li and the electrolyte (garnet) severely limits the development of solid electrolytes. In this study, we synthesize cubic phase Li6.4La3Zr1.4Ta0.6O12 (LLZTO) using a secondary sintering method. In addition, a thin aluminum nitride (AlN) layer is introduced between the metal (Li) and the solid electrolyte. Theoretical calculations show that AlN has a high affinity for Li. Furthermore, it is shown that the AlN coating can effectively reduce the interface impedance between Li and the solid electrolyte and improve the lithium-ion transport. The assembled symmetric Li cells can operate stably for more than 3600 h, unlike the symmetric cells without AlN coating, which short-circuited after only a few cycles. The hybrid solid-state battery with a modified layer, which is assembled using LiFePO4 (LFP), still has a capacity of 120 mAh g−1 after 200 cycles, with a capacity retention rate of 98%. This shows that the introduction of an AlN interlayer is very helpful to obtain a stable Li/solid-electrolyte interface, which improves the cycling stability of the battery.
Top-30
Citations by journals
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Batteries
2 publications, 18.18%
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Nanomaterials
2 publications, 18.18%
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Materials
2 publications, 18.18%
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Small Methods
1 publication, 9.09%
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Electrochem
1 publication, 9.09%
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ACS applied materials & interfaces
1 publication, 9.09%
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Materials Chemistry and Physics
1 publication, 9.09%
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Russian Chemical Reviews
1 publication, 9.09%
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Citations by publishers
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Multidisciplinary Digital Publishing Institute (MDPI)
7 publications, 63.64%
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Wiley
1 publication, 9.09%
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American Chemical Society (ACS)
1 publication, 9.09%
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Elsevier
1 publication, 9.09%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 9.09%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Jiang W. et al. Improvement of the Interface between the Lithium Anode and a Garnet-Type Solid Electrolyte of Lithium Batteries Using an Aluminum-Nitride Layer // Nanomaterials. 2022. Vol. 12. No. 12. p. 2023.
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Jiang W., Dong L., Liu S., Ai B., Zhao S., Zhang W., Pan K., Zhang L. Improvement of the Interface between the Lithium Anode and a Garnet-Type Solid Electrolyte of Lithium Batteries Using an Aluminum-Nitride Layer // Nanomaterials. 2022. Vol. 12. No. 12. p. 2023.
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TY - JOUR
DO - 10.3390/nano12122023
UR - https://doi.org/10.3390/nano12122023
TI - Improvement of the Interface between the Lithium Anode and a Garnet-Type Solid Electrolyte of Lithium Batteries Using an Aluminum-Nitride Layer
T2 - Nanomaterials
AU - Jiang, Wen
AU - Dong, Lingling
AU - Liu, Shuanghui
AU - Ai, Bing
AU - Zhao, Shuangshuang
AU - Pan, Kefeng
AU - Zhang, Lipeng
AU - Zhang, Weimin
PY - 2022
DA - 2022/06/12 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 2023
IS - 12
VL - 12
SN - 2079-4991
ER -
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@article{2022_Jiang,
author = {Wen Jiang and Lingling Dong and Shuanghui Liu and Bing Ai and Shuangshuang Zhao and Kefeng Pan and Lipeng Zhang and Weimin Zhang},
title = {Improvement of the Interface between the Lithium Anode and a Garnet-Type Solid Electrolyte of Lithium Batteries Using an Aluminum-Nitride Layer},
journal = {Nanomaterials},
year = {2022},
volume = {12},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {jun},
url = {https://doi.org/10.3390/nano12122023},
number = {12},
pages = {2023},
doi = {10.3390/nano12122023}
}
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Jiang, Wen, et al. “Improvement of the Interface between the Lithium Anode and a Garnet-Type Solid Electrolyte of Lithium Batteries Using an Aluminum-Nitride Layer.” Nanomaterials, vol. 12, no. 12, Jun. 2022, p. 2023. https://doi.org/10.3390/nano12122023.