Open Access
A Comparison of Hydrogen Storage in Pt, Pd and Pt/Pd Alloys Loaded Disordered Mesoporous Hollow Carbon Spheres
Martyna Baca
1
,
Krzysztof Cendrowski
1
,
Wojciech Kukulka
1
,
Grzegorz Bazarko
1
,
Dariusz Moszyński
2
,
Beata Michalkiewicz
2
,
Ryszard Kalenczuk
1
,
Beata Zielinska
1
Publication type: Journal Article
Publication date: 2018-08-21
PubMed ID:
30134612
General Chemical Engineering
General Materials Science
Abstract
Comprehensive study to evaluate the ability of hydrogen uptake by disordered mesoporous hollow carbon spheres doped witch metal such as Pt, Pd or Pt/Pd was conducted. They were synthesized facilely using sonication and then calcination process under vacuum at the temperature of 550 °C. The effect on hydrogen sorption at neat-ambient conditions (40 °C, up to 45 bar) was thoroughly analyzed. The results clearly revealed that metal functionalization has a significant impact on the hydrogen storage capacity as the mechanism of gas uptake depends on two factors: metal type and certain size of particles. Thus, functionalized spheres adsorb hydrogen by physisorption forming metal hydrides or metal hydrides combined with hydrogen spillover effect. As a result, a sample with narrower distribution of nanoparticles and smaller specific size exhibited enhanced hydrogen uptake.
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36
Total citations:
36
Citations from 2025:
10
(27.78%)
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GOST
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Baca M. et al. A Comparison of Hydrogen Storage in Pt, Pd and Pt/Pd Alloys Loaded Disordered Mesoporous Hollow Carbon Spheres // Nanomaterials. 2018. Vol. 8. No. 9. p. 639.
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Baca M., Cendrowski K., Kukulka W., Bazarko G., Moszyński D., Michalkiewicz B., Kalenczuk R., Zielinska B. A Comparison of Hydrogen Storage in Pt, Pd and Pt/Pd Alloys Loaded Disordered Mesoporous Hollow Carbon Spheres // Nanomaterials. 2018. Vol. 8. No. 9. p. 639.
Cite this
RIS
Copy
TY - JOUR
DO - 10.3390/nano8090639
UR - https://doi.org/10.3390/nano8090639
TI - A Comparison of Hydrogen Storage in Pt, Pd and Pt/Pd Alloys Loaded Disordered Mesoporous Hollow Carbon Spheres
T2 - Nanomaterials
AU - Baca, Martyna
AU - Cendrowski, Krzysztof
AU - Kukulka, Wojciech
AU - Bazarko, Grzegorz
AU - Moszyński, Dariusz
AU - Michalkiewicz, Beata
AU - Kalenczuk, Ryszard
AU - Zielinska, Beata
PY - 2018
DA - 2018/08/21
PB - MDPI
SP - 639
IS - 9
VL - 8
PMID - 30134612
SN - 2079-4991
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Baca,
author = {Martyna Baca and Krzysztof Cendrowski and Wojciech Kukulka and Grzegorz Bazarko and Dariusz Moszyński and Beata Michalkiewicz and Ryszard Kalenczuk and Beata Zielinska},
title = {A Comparison of Hydrogen Storage in Pt, Pd and Pt/Pd Alloys Loaded Disordered Mesoporous Hollow Carbon Spheres},
journal = {Nanomaterials},
year = {2018},
volume = {8},
publisher = {MDPI},
month = {aug},
url = {https://doi.org/10.3390/nano8090639},
number = {9},
pages = {639},
doi = {10.3390/nano8090639}
}
Cite this
MLA
Copy
Baca, Martyna, et al. “A Comparison of Hydrogen Storage in Pt, Pd and Pt/Pd Alloys Loaded Disordered Mesoporous Hollow Carbon Spheres.” Nanomaterials, vol. 8, no. 9, Aug. 2018, p. 639. https://doi.org/10.3390/nano8090639.