Open Access
Polymers, volume 15, issue 22, pages 4340
Nafion-212 Membrane Solvated by Ethylene and Propylene Carbonates as Electrolyte for Lithium Metal Batteries
Publication type: Journal Article
Publication date: 2023-11-07
General Chemistry
Polymers and Plastics
Abstract
The use of cation-exchange membranes as electrolytes for lithium metal batteries can prevent the formation of lithium dendrites during extended cycling and guarantee safe battery operation. In our study, the Nafion-212 membrane in lithium form solvated by a mixture of ethylene carbonate and propylene carbonate (EC-PC) was used as an electrolyte in a lithium metal battery with the LiFePO4 cathode. The Nafion-212-EC-PC electrolyte is electrochemically stable up to 6 V, indicating its suitability for high-energy density batteries. It has an ionic conductivity of 1.9 × 10−4 S/cm at 25 °C and a high lithium transference number. The symmetric Li|Nafion-212-EC-PC|Li cell shows a very low overvoltage of ~0.3 V at a current density of ±0.1 mA/cm2. At 25 °C, the LiFePO4|Nafion-212-EC-PC|Li battery exhibits a capacity of 141, 136, 125, and 100 mAh/g at 0.1, 0.2, 0.5, and 1C rates, respectively. It maintains a capacity of 120 mAh/g at 0 °C and 0.1C with stable performance for 50 charge/discharge cycles. The mechanism of conductivity and capacity retention at low temperatures is discussed.
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Russian Chemical Reviews
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
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Voropaeva D. et al. Nafion-212 Membrane Solvated by Ethylene and Propylene Carbonates as Electrolyte for Lithium Metal Batteries // Polymers. 2023. Vol. 15. No. 22. p. 4340.
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Voropaeva D., Novikova S. I., Stenina I. A., Yaroslavtsev A. B. Nafion-212 Membrane Solvated by Ethylene and Propylene Carbonates as Electrolyte for Lithium Metal Batteries // Polymers. 2023. Vol. 15. No. 22. p. 4340.
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TY - JOUR
DO - 10.3390/polym15224340
UR - https://doi.org/10.3390/polym15224340
TI - Nafion-212 Membrane Solvated by Ethylene and Propylene Carbonates as Electrolyte for Lithium Metal Batteries
T2 - Polymers
AU - Voropaeva, Daria
AU - Novikova, Svetlana I.
AU - Stenina, Irina A
AU - Yaroslavtsev, A. B.
PY - 2023
DA - 2023/11/07 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 4340
IS - 22
VL - 15
SN - 2073-4360
ER -
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@article{2023_Voropaeva,
author = {Daria Voropaeva and Svetlana I. Novikova and Irina A Stenina and A. B. Yaroslavtsev},
title = {Nafion-212 Membrane Solvated by Ethylene and Propylene Carbonates as Electrolyte for Lithium Metal Batteries},
journal = {Polymers},
year = {2023},
volume = {15},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {nov},
url = {https://doi.org/10.3390/polym15224340},
number = {22},
pages = {4340},
doi = {10.3390/polym15224340}
}
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Voropaeva, Daria, et al. “Nafion-212 Membrane Solvated by Ethylene and Propylene Carbonates as Electrolyte for Lithium Metal Batteries.” Polymers, vol. 15, no. 22, Nov. 2023, p. 4340. https://doi.org/10.3390/polym15224340.