Open Access
Polymers, volume 9, issue 10, pages 515
A Single-Site Iron(III)-Salan Catalyst for Converting COS to Sulfur-Containing Polymers
Publication type: Journal Article
Publication date: 2017-10-17
PubMed ID:
30965818
General Chemistry
Polymers and Plastics
Abstract
An iron(III) complex of tetradentate N,N′-disubstituted bis(aminophenoxide) (designated as salan, a saturated version of the corresponding salen ligand) with a sterically hindered organic base anchored on the ligand framework, can selectively mediate the conversion of carbonyl sulfide to sulfur-containing polymers by the copolymerization with epoxides. This single-site catalyst exhibits broad substrate scope, and the resultant copolymers have completely alternating structures. In addition, this catalyst is efficient in producing diblock copolymers, suggesting a living polymerization nature.
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GOST
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Gu G. et al. A Single-Site Iron(III)-Salan Catalyst for Converting COS to Sulfur-Containing Polymers // Polymers. 2017. Vol. 9. No. 10. p. 515.
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Gu G., Yue T. J., Wan Z. Q., Zhang R., Lu X., Ren W. A Single-Site Iron(III)-Salan Catalyst for Converting COS to Sulfur-Containing Polymers // Polymers. 2017. Vol. 9. No. 10. p. 515.
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TY - JOUR
DO - 10.3390/polym9100515
UR - https://doi.org/10.3390/polym9100515
TI - A Single-Site Iron(III)-Salan Catalyst for Converting COS to Sulfur-Containing Polymers
T2 - Polymers
AU - Gu, Ge-Ge
AU - Yue, Tian Jun
AU - Wan, Zhao Qian
AU - Zhang, Rong
AU - Lu, Xiao-Bing
AU - Ren, Wei-Min
PY - 2017
DA - 2017/10/17
PB - MDPI
SP - 515
IS - 10
VL - 9
PMID - 30965818
SN - 2073-4360
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Gu,
author = {Ge-Ge Gu and Tian Jun Yue and Zhao Qian Wan and Rong Zhang and Xiao-Bing Lu and Wei-Min Ren},
title = {A Single-Site Iron(III)-Salan Catalyst for Converting COS to Sulfur-Containing Polymers},
journal = {Polymers},
year = {2017},
volume = {9},
publisher = {MDPI},
month = {oct},
url = {https://doi.org/10.3390/polym9100515},
number = {10},
pages = {515},
doi = {10.3390/polym9100515}
}
Cite this
MLA
Copy
Gu, Ge-Ge, et al. “A Single-Site Iron(III)-Salan Catalyst for Converting COS to Sulfur-Containing Polymers.” Polymers, vol. 9, no. 10, Oct. 2017, p. 515. https://doi.org/10.3390/polym9100515.