Open Access
Processes, volume 10, issue 12, pages 2509
Polystyrene-Based Single-Ion Conducting Polymer Electrolyte for Lithium Metal Batteries
Publication type: Journal Article
Publication date: 2022-11-25
Process Chemistry and Technology
Bioengineering
Chemical Engineering (miscellaneous)
Abstract
Lithium metal batteries are one of the more promising replacements for lithium-ion batteries owing to their ability to reach high energy densities. The main problem limiting their commercial application is the formation of dendrites, which significantly reduces their durability and renders the batteries unsafe. In the present work, we used a single-ion conducting gel polymer electrolyte based on a poly(ethylene-ran-butylene)-block-polystyrene (SEBS) block copolymer, which was functionalized with benzenesulfonylimide anions and plasticized by a mixture of ethylene carbonate and dimethylacetamide (SSEBS-Ph-EC-DMA), with a solvent uptake of 160% (~12 solvent molecules per one functional group of the membrane). The SSEBS-Ph-EC-DMA electrolyte exhibits an ionic conductivity of 0.6 mSm∙cm−1 at 25 °C and appears to be a cationic conductor (TLi+ = 0.72). SSEBS-Ph-EC-DMA is electrochemically stable up to 4.1 V. Symmetrical Li|Li cells; further, with regard to SSEBS-Ph-EC-DMA membrane electrolytes, it showed a good performance (~0.10 V at first cycles and <0.23 V after 700 h of cycling at ±0.1 mA∙cm−2 and ±0.05 mAh∙cm−2). The LiFePO4|SSEBS-Ph-EC-DMA|Li battery showed discharge capacity values of 100 mAh∙g−1 and a 100% Coulomb efficiency, at a cycling rate of 0.1C.
Top-30
Citations by journals
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Batteries
1 publication, 14.29%
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Polymers
1 publication, 14.29%
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eTransportation
1 publication, 14.29%
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Journal of Physical Chemistry C
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European Polymer Journal
1 publication, 14.29%
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Russian Chemical Reviews
1 publication, 14.29%
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Citations by publishers
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2
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 28.57%
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Elsevier
2 publications, 28.57%
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American Chemical Society (ACS)
1 publication, 14.29%
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Springer Nature
1 publication, 14.29%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 14.29%
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Voropaeva D. et al. Polystyrene-Based Single-Ion Conducting Polymer Electrolyte for Lithium Metal Batteries // Processes. 2022. Vol. 10. No. 12. p. 2509.
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Voropaeva D., Novikova S., Trofimenko N., Yaroslavtsev A. B. Polystyrene-Based Single-Ion Conducting Polymer Electrolyte for Lithium Metal Batteries // Processes. 2022. Vol. 10. No. 12. p. 2509.
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TY - JOUR
DO - 10.3390/pr10122509
UR - https://doi.org/10.3390/pr10122509
TI - Polystyrene-Based Single-Ion Conducting Polymer Electrolyte for Lithium Metal Batteries
T2 - Processes
AU - Voropaeva, Daria
AU - Novikova, Svetlana
AU - Trofimenko, Nikolay
AU - Yaroslavtsev, A. B.
PY - 2022
DA - 2022/11/25 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 2509
IS - 12
VL - 10
SN - 2227-9717
ER -
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@article{2022_Voropaeva,
author = {Daria Voropaeva and Svetlana Novikova and Nikolay Trofimenko and A. B. Yaroslavtsev},
title = {Polystyrene-Based Single-Ion Conducting Polymer Electrolyte for Lithium Metal Batteries},
journal = {Processes},
year = {2022},
volume = {10},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {nov},
url = {https://doi.org/10.3390/pr10122509},
number = {12},
pages = {2509},
doi = {10.3390/pr10122509}
}
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Voropaeva, Daria, et al. “Polystyrene-Based Single-Ion Conducting Polymer Electrolyte for Lithium Metal Batteries.” Processes, vol. 10, no. 12, Nov. 2022, p. 2509. https://doi.org/10.3390/pr10122509.