Open Access
2-Pyridylselenenyl versus 2-Pyridyltellurenyl Halides: Symmetrical Chalcogen Bonding in the Solid State and Reactivity towards Nitriles
Ivan V Buslov
1
,
Victor N. Khrustalev
1, 3
,
Mariya V Grudova
1
,
Zhanna V. Matsulevich
5
,
Alexander V. Borisov
5
,
Julia M. Lukiyanova
5
,
Maria M. Grishina
1
,
Anatoly A Kirichuk
1
,
Tatiyana V Serebryanskaya
6
,
Alexander G. Tskhovrebov
1, 7
3
5
Publication type: Journal Article
Publication date: 2021-12-07
Chemistry (miscellaneous)
Physics and Astronomy (miscellaneous)
General Mathematics
Computer Science (miscellaneous)
Abstract
The synthesis of 2-pyridyltellurenyl bromide via Br2 oxidative cleavage of the Te–Te bond of dipyridylditelluride is reported. Single-crystal X-ray diffraction analysis of 2-pyridyltellurenyl bromide demonstrated that the Te atom of 2-pyridyltellurenyl bromide was involved in four different noncovalent contacts: Te⋯Te interactions, two Te⋯Br ChB, and one Te⋯N ChB contact forming 3D supramolecular symmetrical framework. In contrast to 2-pyridylselenenyl halides, the Te congener does not react with nitriles furnishing cyclization products. 2-Pyridylselenenyl chloride was demonstrated to easily form the corresponding adduct with benzonitrile. The cyclization product was studied by the single-crystal X-ray diffraction analysis, which revealed that in contrast to earlier studied cationic 1,2,4-selenadiazoles, here we observed that the adduct with benzonitrile formed supramolecular dimers via Se⋯Se interactions in the solid state, which were never observed before for 1,2,4-selenadiazoles.
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21
Total citations:
21
Citations from 2025:
1
(5%)
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Buslov I. V. et al. 2-Pyridylselenenyl versus 2-Pyridyltellurenyl Halides: Symmetrical Chalcogen Bonding in the Solid State and Reactivity towards Nitriles // Symmetry. 2021. Vol. 13. No. 12. p. 2350.
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Buslov I. V., Novikov A. S., Khrustalev V. N., Grudova M. V., Kubasov A. S., Matsulevich Z. V., Borisov A. V., Lukiyanova J. M., Grishina M. M., Kirichuk A. A., Serebryanskaya T. V., Kritchenkov A. S., Tskhovrebov A. G. 2-Pyridylselenenyl versus 2-Pyridyltellurenyl Halides: Symmetrical Chalcogen Bonding in the Solid State and Reactivity towards Nitriles // Symmetry. 2021. Vol. 13. No. 12. p. 2350.
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RIS
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TY - JOUR
DO - 10.3390/sym13122350
UR - https://doi.org/10.3390/sym13122350
TI - 2-Pyridylselenenyl versus 2-Pyridyltellurenyl Halides: Symmetrical Chalcogen Bonding in the Solid State and Reactivity towards Nitriles
T2 - Symmetry
AU - Buslov, Ivan V
AU - Novikov, Alexander S.
AU - Khrustalev, Victor N.
AU - Grudova, Mariya V
AU - Kubasov, Alexey S.
AU - Matsulevich, Zhanna V.
AU - Borisov, Alexander V.
AU - Lukiyanova, Julia M.
AU - Grishina, Maria M.
AU - Kirichuk, Anatoly A
AU - Serebryanskaya, Tatiyana V
AU - Kritchenkov, Andreii S
AU - Tskhovrebov, Alexander G.
PY - 2021
DA - 2021/12/07
PB - MDPI
SP - 2350
IS - 12
VL - 13
SN - 2073-8994
ER -
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BibTex (up to 50 authors)
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@article{2021_Buslov,
author = {Ivan V Buslov and Alexander S. Novikov and Victor N. Khrustalev and Mariya V Grudova and Alexey S. Kubasov and Zhanna V. Matsulevich and Alexander V. Borisov and Julia M. Lukiyanova and Maria M. Grishina and Anatoly A Kirichuk and Tatiyana V Serebryanskaya and Andreii S Kritchenkov and Alexander G. Tskhovrebov},
title = {2-Pyridylselenenyl versus 2-Pyridyltellurenyl Halides: Symmetrical Chalcogen Bonding in the Solid State and Reactivity towards Nitriles},
journal = {Symmetry},
year = {2021},
volume = {13},
publisher = {MDPI},
month = {dec},
url = {https://doi.org/10.3390/sym13122350},
number = {12},
pages = {2350},
doi = {10.3390/sym13122350}
}
Cite this
MLA
Copy
Buslov, Ivan V., et al. “2-Pyridylselenenyl versus 2-Pyridyltellurenyl Halides: Symmetrical Chalcogen Bonding in the Solid State and Reactivity towards Nitriles.” Symmetry, vol. 13, no. 12, Dec. 2021, p. 2350. https://doi.org/10.3390/sym13122350.