Open Access
Beilstein Journal of Organic Chemistry, volume 11, pages 1469-1474
Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene
Publication type: Journal Article
Publication date: 2015-08-21
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.7
ISSN: 18605397, 18605397
Organic Chemistry
Abstract
Differential scanning calorimetry (DSC) analysis of ring opening methatesis polymerization (ROMP) derived polydicyclopentadiene (PDCPD) revealed an unexpected thermal behavior. A recurring exothermic signal can be observed in the DSC analysis after an elapsed time period. This exothermic signal was found to be proportional to the resting period and was accompanied by a constant increase in the glass-transition temperature. We hypothesize that a relaxation mechanism within the cross-linked scaffold, together with a long-lived stable ruthenium alkylidene species are responsible for the observed phenomenon.
Top-30
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Citations by publishers
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9 publications, 45%
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5 publications, 25%
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1 publication, 5%
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- We do not take into account publications without a DOI.
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Vidavsky Y. et al. Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene // Beilstein Journal of Organic Chemistry. 2015. Vol. 11. pp. 1469-1474.
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Vidavsky Y., Navon Y., Ginzburg Y., Gottlieb M., Lemcoff N. G. Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene // Beilstein Journal of Organic Chemistry. 2015. Vol. 11. pp. 1469-1474.
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TY - JOUR
DO - 10.3762/bjoc.11.159
UR - https://doi.org/10.3762/bjoc.11.159
TI - Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene
T2 - Beilstein Journal of Organic Chemistry
AU - Vidavsky, Yuval
AU - Navon, Yotam
AU - Ginzburg, Yakov
AU - Gottlieb, Moshe
AU - Lemcoff, N Gabriel
PY - 2015
DA - 2015/08/21 00:00:00
PB - Beilstein-Institut
SP - 1469-1474
VL - 11
SN - 1860-5397
SN - 1860-5397
ER -
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@article{2015_Vidavsky,
author = {Yuval Vidavsky and Yotam Navon and Yakov Ginzburg and Moshe Gottlieb and N Gabriel Lemcoff},
title = {Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene},
journal = {Beilstein Journal of Organic Chemistry},
year = {2015},
volume = {11},
publisher = {Beilstein-Institut},
month = {aug},
url = {https://doi.org/10.3762/bjoc.11.159},
pages = {1469--1474},
doi = {10.3762/bjoc.11.159}
}