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volume 11 pages 2297-2305

Cu(I)-catalyzed N,N'-diarylation of natural diamines and polyamines with aryl iodides

Publication typeJournal Article
Publication date2015-11-24
scimago Q2
wos Q3
SJR0.482
CiteScore3.8
Impact factor2.1
ISSN18605397
PubMed ID:  26734078
Organic Chemistry
Abstract

The Cu(I)-catalyzed N,N’-diarylation of natural diamines and polyamines such as putrescine, cadaverine, spermine, spermidine and their homologues is described. Aryl iodides bearing electron-donating and electron-withdrawing groups have been employed in the study. The CuI/2-(isobutyryl)cyclohexanone/DMF catalytic system has found to be more efficient in the diarylation of diamines and spermine while the CuI/L-proline/EtCN system proved to be preferable for the diarylation of other tri- and tetraamines like spermidine, norspermidine and norspermine.

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Panchenko S. P. et al. Cu(I)-catalyzed N,N'-diarylation of natural diamines and polyamines with aryl iodides // Beilstein Journal of Organic Chemistry. 2015. Vol. 11. pp. 2297-2305.
GOST all authors (up to 50) Copy
Panchenko S. P., Anokhin M. V., Maloshitskaya O. A., Averin A. A., Beletskaya I. P. Cu(I)-catalyzed N,N'-diarylation of natural diamines and polyamines with aryl iodides // Beilstein Journal of Organic Chemistry. 2015. Vol. 11. pp. 2297-2305.
RIS |
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RIS Copy
TY - JOUR
DO - 10.3762/bjoc.11.250
UR - https://doi.org/10.3762/bjoc.11.250
TI - Cu(I)-catalyzed N,N'-diarylation of natural diamines and polyamines with aryl iodides
T2 - Beilstein Journal of Organic Chemistry
AU - Panchenko, Svetlana Petrovna
AU - Anokhin, Maksim Viktorovich
AU - Maloshitskaya, Olga Aleksandrovna
AU - Averin, Alexey A
AU - Beletskaya, Irina P.
PY - 2015
DA - 2015/11/24
PB - Beilstein-Institut
SP - 2297-2305
VL - 11
PMID - 26734078
SN - 1860-5397
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Panchenko,
author = {Svetlana Petrovna Panchenko and Maksim Viktorovich Anokhin and Olga Aleksandrovna Maloshitskaya and Alexey A Averin and Irina P. Beletskaya},
title = {Cu(I)-catalyzed N,N'-diarylation of natural diamines and polyamines with aryl iodides},
journal = {Beilstein Journal of Organic Chemistry},
year = {2015},
volume = {11},
publisher = {Beilstein-Institut},
month = {nov},
url = {https://doi.org/10.3762/bjoc.11.250},
pages = {2297--2305},
doi = {10.3762/bjoc.11.250}
}