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Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes

Тип публикацииJournal Article
Дата публикации2021-01-27
scimago Q2
wos Q3
БС2
SJR0.482
CiteScore3.8
Impact factor2.1
ISSN18605397
Organic Chemistry
Краткое описание

The Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic 1,3-dienes was investigated. A series of novel monofluorinated norbornenes was prepared in up to 97% yield. The reaction with 1,3-cyclohexadiene permits the preparation of monofluorinated bicyclo[2.2.2]oct-2-enes. The kinetic data of the reactions with 1,3-cyclopentadiene and 1,3-cyclohexadiene were used to calculate activation parameters. Furthermore, the synthetic utility of the cycloadducts obtained was demonstrated.

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ГОСТ |
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Ponomarev S. A. et al. Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes // Beilstein Journal of Organic Chemistry. 2021. Vol. 17. pp. 283-292.
ГОСТ со всеми авторами (до 50) Скопировать
Ponomarev S. A., Larkovich R. V., Aldoshin A. S., Tabolin A. A., Ioffe S. L., Groß J., Opatz T., Nenajdenko V. G. Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes // Beilstein Journal of Organic Chemistry. 2021. Vol. 17. pp. 283-292.
RIS |
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TY - JOUR
DO - 10.3762/bjoc.17.27
UR - https://doi.org/10.3762/bjoc.17.27
TI - Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes
T2 - Beilstein Journal of Organic Chemistry
AU - Ponomarev, Savva A
AU - Larkovich, Roman V
AU - Aldoshin, Alexander S
AU - Tabolin, Andrey A
AU - Ioffe, Sema L.
AU - Groß, Jonathan
AU - Opatz, Till
AU - Nenajdenko, Valentine G.
PY - 2021
DA - 2021/01/27
PB - Beilstein-Institut
SP - 283-292
VL - 17
PMID - 33564337
SN - 1860-5397
ER -
BibTex
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BibTex (до 50 авторов) Скопировать
@article{2021_Ponomarev,
author = {Savva A Ponomarev and Roman V Larkovich and Alexander S Aldoshin and Andrey A Tabolin and Sema L. Ioffe and Jonathan Groß and Till Opatz and Valentine G. Nenajdenko},
title = {Diels–Alder reaction of β-fluoro-β-nitrostyrenes with cyclic dienes},
journal = {Beilstein Journal of Organic Chemistry},
year = {2021},
volume = {17},
publisher = {Beilstein-Institut},
month = {jan},
url = {https://doi.org/10.3762/bjoc.17.27},
pages = {283--292},
doi = {10.3762/bjoc.17.27}
}