Open Access
Macroheterocycles, volume 14, issue 1, pages 51-58
Unusual cyan-purple electrochromism of sandwich phthalocyaninates observed on the example of µ-carbido diruthenium(Iv) complex
Publication type: Journal Article
Publication date: 2021-06-25
Journal:
Macroheterocycles
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 1.4
ISSN: 19989539, 27131092
Organic Chemistry
Analytical Chemistry
Abstract
Current research in sandwich phthalocyaninates enjoys increasing interest due to peculiar properties of these compounds, i.e. their intense coloration and ability to change and control it via redox processes. Obviously, such effect found its application in development of electrochromic devices. In the case of commonly studied rare earth element bisphthalocyaninates, the most dominant electrochromic palette observed for them lies within the red-green-blue gamut. In this work, we report that an unusual sandwich – covalently-bridged μ-carbido diruthenium(IV) bisphthalocyaninate – exhibits equally unusual color changes upon its reversible electrochemical oxidation/reduction, namely switching from cyan to purple. The study provides a detailed spectroelectrochemical characterization of this μ-carbido-dimeric complex in solution, in thin cast and ultrathin Langmuir-Schaefer films, which all demonstrate aforementioned variable vibrant coloration in action.
Citations by journals
|
1
|
|
|
Protection of Metals and Physical Chemistry of Surfaces
|
Protection of Metals and Physical Chemistry of Surfaces
1 publication, 33.33%
|
|
Colloid Journal
|
Colloid Journal
1 publication, 33.33%
|
|
Polyhedron
|
Polyhedron
1 publication, 33.33%
|
|
1
|
Citations by publishers
|
1
2
|
|
|
Pleiades Publishing
|
Pleiades Publishing
2 publications, 66.67%
|
|
Elsevier
|
Elsevier
1 publication, 33.33%
|
|
1
2
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[1,1,0,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["33.33","33.33",0,"33.33"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Protection of Metals and Physical Chemistry of Surfaces","Colloid Journal","Polyhedron"],"ids":[15318,3923,21269],"codes":[0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,33.33,33.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Pleiades Publishing","Elsevier"],"ids":[101,17],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[2,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[66.67,33.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Kutsybala D. S. et al. Unusual cyan-purple electrochromism of sandwich phthalocyaninates observed on the example of µ-carbido diruthenium(Iv) complex // Macroheterocycles. 2021. Vol. 14. No. 1. pp. 51-58.
GOST all authors (up to 50)
Copy
Kutsybala D. S., Shokurov A. V., Kroitor A. P., Martynov A. G., Selektor S. L., Gorbunova Y. G., Tsivadze A. Y. Unusual cyan-purple electrochromism of sandwich phthalocyaninates observed on the example of µ-carbido diruthenium(Iv) complex // Macroheterocycles. 2021. Vol. 14. No. 1. pp. 51-58.
Cite this
RIS
Copy
TY - JOUR
DO - 10.6060/mhc210234s
UR - https://doi.org/10.6060%2Fmhc210234s
TI - Unusual cyan-purple electrochromism of sandwich phthalocyaninates observed on the example of µ-carbido diruthenium(Iv) complex
T2 - Macroheterocycles
AU - Kutsybala, Daria S
AU - Shokurov, Alexander V
AU - Kroitor, Andrey P
AU - Martynov, Alexander G.
AU - Selektor, Sofia L
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan Yu.
PY - 2021
DA - 2021/06/25 00:00:00
PB - Ivanovo State University of Chemistry and Technology
SP - 51-58
IS - 1
VL - 14
SN - 1998-9539
SN - 2713-1092
ER -
Cite this
BibTex
Copy
@article{2021_Kutsybala,
author = {Daria S Kutsybala and Alexander V Shokurov and Andrey P Kroitor and Alexander G. Martynov and Sofia L Selektor and Yulia G. Gorbunova and Aslan Yu. Tsivadze},
title = {Unusual cyan-purple electrochromism of sandwich phthalocyaninates observed on the example of µ-carbido diruthenium(Iv) complex},
journal = {Macroheterocycles},
year = {2021},
volume = {14},
publisher = {Ivanovo State University of Chemistry and Technology},
month = {jun},
url = {https://doi.org/10.6060%2Fmhc210234s},
number = {1},
pages = {51--58},
doi = {10.6060/mhc210234s}
}
Cite this
MLA
Copy
Kutsybala, Daria S., et al. “Unusual cyan-purple electrochromism of sandwich phthalocyaninates observed on the example of µ-carbido diruthenium(Iv) complex.” Macroheterocycles, vol. 14, no. 1, Jun. 2021, pp. 51-58. https://doi.org/10.6060%2Fmhc210234s.