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Copper-catalyzed amination in the synthesis of polyoxadiamine derivatives of aza- and diazacrown ethers
Publication type: Journal Article
Publication date: 2014-01-01
scimago Q4
wos Q3
SJR: 0.193
CiteScore: 1.5
Impact factor: 1.2
ISSN: 19989539, 27131092
Organic Chemistry
Analytical Chemistry
Abstract
Cu(I)-Catalyzed amination of N-(iodobenzyl) substituted azacrown ethers with propane-1,3-diamine and several polyoxadiamines was investigated. In the case of diamine excess and the use of CuI/l-proline catalytic system in EtCN the formation of the compounds with one azacrown and one diamine moieties was observed. When taking the excess of N-(iodobenzyl) derivative of azacrown ether and CuI/2-(isobutyryl)cyclohexanone catalytic system in DMF, bis(azacrown) substituted oxadiamine could be obtained. Amination of N,N’-di(iodobenzyl) substituted diazacrown ether was studied under the same conditions. The comparison of Pd(0)- with Cu(I)-mediated amination reactions was done using N-(bromobenzyl) substituted azacrown ethers.
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Yakushev A. A. Y. et al. Copper-catalyzed amination in the synthesis of polyoxadiamine derivatives of aza- and diazacrown ethers // Macroheterocycles. 2014. Vol. 7. No. 4. pp. 358-364.
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Yakushev A. A. Y., Averin A. D., Anokhin M. V., Maloshitskaya O. A., Lamaty F., Beletskaya I. P. Copper-catalyzed amination in the synthesis of polyoxadiamine derivatives of aza- and diazacrown ethers // Macroheterocycles. 2014. Vol. 7. No. 4. pp. 358-364.
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TY - JOUR
DO - 10.6060/mhc141035a
UR - https://doi.org/10.6060/mhc141035a
TI - Copper-catalyzed amination in the synthesis of polyoxadiamine derivatives of aza- and diazacrown ethers
T2 - Macroheterocycles
AU - Yakushev, Alexei A Yakushev
AU - Averin, Alexei D.
AU - Anokhin, Maxim V
AU - Maloshitskaya, Olga A
AU - Lamaty, Frédéric
AU - Beletskaya, Irina P.
PY - 2014
DA - 2014/01/01
PB - Ivanovo State University of Chemistry and Technology
SP - 358-364
IS - 4
VL - 7
SN - 1998-9539
SN - 2713-1092
ER -
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@article{2014_Yakushev,
author = {Alexei A Yakushev Yakushev and Alexei D. Averin and Maxim V Anokhin and Olga A Maloshitskaya and Frédéric Lamaty and Irina P. Beletskaya},
title = {Copper-catalyzed amination in the synthesis of polyoxadiamine derivatives of aza- and diazacrown ethers},
journal = {Macroheterocycles},
year = {2014},
volume = {7},
publisher = {Ivanovo State University of Chemistry and Technology},
month = {jan},
url = {https://doi.org/10.6060/mhc141035a},
number = {4},
pages = {358--364},
doi = {10.6060/mhc141035a}
}
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Yakushev, Alexei A. Yakushev, et al. “Copper-catalyzed amination in the synthesis of polyoxadiamine derivatives of aza- and diazacrown ethers.” Macroheterocycles, vol. 7, no. 4, Jan. 2014, pp. 358-364. https://doi.org/10.6060/mhc141035a.
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