Macroheterocycles, volume 13, issue 1, pages 44-54
The Spatial Structure of Macroheterocyclic Compounds, as a Key Factor Affecting the Course of the Macrocyclization Reaction
Publication type: Journal Article
Publication date: 2020-05-19
Journal:
Macroheterocycles
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 1.4
ISSN: 19989539, 27131092
Organic Chemistry
Analytical Chemistry
Abstract
Nowadays the macrocyclization reaction is often used for the synthesis of new macroheterocyclic compounds. This is a one-pot reaction, carried out in one stage, which makes it the most convenient and efficient in the synthesis of complex macroheterocyclic compounds. One of the key parameters in the selection of synthesis conditions is the spatial structure and conformational composition of the synthesized compounds. The fact is that if the certain structure prevails in the solution, then it is the most energetically favorable, i.e. its potential energy is minimal and therefore it is necessary to spend less energy to synthesis of this compound. The structure, obtained during the synthesis process, largely depends on what solvent is used. In this work, it was shown that the conformational composition of the macroheterocyclic model compound in various solvents differs by 10–20 %. This fact must be taken into account when conducting macrocyclization reactions not only for the model compound presented in this paper, but also for other substances consisting of macroheterocyclic molecules, such as crown ethers, cyclosporine, calixarenes, and other classes of compounds having a non-rigid structure.
Citations by journals
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Russian Journal of Physical Chemistry B
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Russian Journal of Physical Chemistry B
3 publications, 37.5%
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Journal of Molecular Liquids
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Journal of Molecular Liquids
2 publications, 25%
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Russian Journal of Physical Chemistry A
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Russian Journal of Physical Chemistry A
1 publication, 12.5%
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Pharmaceutics
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Pharmaceutics
1 publication, 12.5%
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Materials
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Materials
1 publication, 12.5%
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Citations by publishers
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Pleiades Publishing
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Pleiades Publishing
4 publications, 50%
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Elsevier
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Elsevier
2 publications, 25%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 25%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Belov K. V. et al. The Spatial Structure of Macroheterocyclic Compounds, as a Key Factor Affecting the Course of the Macrocyclization Reaction // Macroheterocycles. 2020. Vol. 13. No. 1. pp. 44-54.
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Belov K. V., Eremeev I. Е., Sobornova V. V., Klochkov V. V., Khodov I. A. The Spatial Structure of Macroheterocyclic Compounds, as a Key Factor Affecting the Course of the Macrocyclization Reaction // Macroheterocycles. 2020. Vol. 13. No. 1. pp. 44-54.
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TY - JOUR
DO - 10.6060/mhc200388k
UR - https://doi.org/10.6060%2Fmhc200388k
TI - The Spatial Structure of Macroheterocyclic Compounds, as a Key Factor Affecting the Course of the Macrocyclization Reaction
T2 - Macroheterocycles
AU - Belov, Konstantin V.
AU - Eremeev, Ilya Е
AU - Sobornova, Valentina V
AU - Klochkov, Vladimir V.
AU - Khodov, Ilya A.
PY - 2020
DA - 2020/05/19 00:00:00
PB - Ivanovo State University of Chemistry and Technology
SP - 44-54
IS - 1
VL - 13
SN - 1998-9539
SN - 2713-1092
ER -
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@article{2020_Belov,
author = {Konstantin V. Belov and Ilya Е Eremeev and Valentina V Sobornova and Vladimir V. Klochkov and Ilya A. Khodov},
title = {The Spatial Structure of Macroheterocyclic Compounds, as a Key Factor Affecting the Course of the Macrocyclization Reaction},
journal = {Macroheterocycles},
year = {2020},
volume = {13},
publisher = {Ivanovo State University of Chemistry and Technology},
month = {may},
url = {https://doi.org/10.6060%2Fmhc200388k},
number = {1},
pages = {44--54},
doi = {10.6060/mhc200388k}
}
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Belov, Konstantin V., et al. “The Spatial Structure of Macroheterocyclic Compounds, as a Key Factor Affecting the Course of the Macrocyclization Reaction.” Macroheterocycles, vol. 13, no. 1, May. 2020, pp. 44-54. https://doi.org/10.6060%2Fmhc200388k.
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