Electrophilic hexa(methoxycarbonyl)cycloheptatrienyl anion in the synthesis of electron-deficient 5-hydroxyisoquinolones
Publication type: Journal Article
Publication date: 2025-02-18
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
Abstract
The reaction of hexa(methoxycarbonyl)cycloheptatrienyl anion with amines affords 5-hydroxyisoquinolones bearing four 4,6,7,8-positioned methoxycarbonyl groups and having unsubstituted C<sup>3</sup>H unit. The reaction is selective due to better steric availability and both charge and orbital distribution within the seven-membered ring and may proceed through a nucleophilic attack on the allyl-anionic moiety.
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Total citations:
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Citations from 2025:
2
(100%)
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Belyy A. Yu. et al. Electrophilic hexa(methoxycarbonyl)cycloheptatrienyl anion in the synthesis of electron-deficient 5-hydroxyisoquinolones // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 162-164.
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Belyy A. Yu., Sokolova A. D., Salikov R. F., Litvinenko V. V., Platonov D. N., Tomilov Y. V. Electrophilic hexa(methoxycarbonyl)cycloheptatrienyl anion in the synthesis of electron-deficient 5-hydroxyisoquinolones // Mendeleev Communications. 2025. Vol. 35. No. 2. pp. 162-164.
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TY - JOUR
DO - 10.71267/mencom.7616
UR - https://www.mathnet.ru/mendc1387
TI - Electrophilic hexa(methoxycarbonyl)cycloheptatrienyl anion in the synthesis of electron-deficient 5-hydroxyisoquinolones
T2 - Mendeleev Communications
AU - Belyy, Alexander Yu
AU - Sokolova, Alena D
AU - Salikov, Rinat Faritovich
AU - Litvinenko, Veronika V
AU - Platonov, Dmitry Nikolaevich
AU - Tomilov, Yury V.
PY - 2025
DA - 2025/02/18
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 162-164
IS - 2
VL - 35
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2025_Belyy,
author = {Alexander Yu Belyy and Alena D Sokolova and Rinat Faritovich Salikov and Veronika V Litvinenko and Dmitry Nikolaevich Platonov and Yury V. Tomilov},
title = {Electrophilic hexa(methoxycarbonyl)cycloheptatrienyl anion in the synthesis of electron-deficient 5-hydroxyisoquinolones},
journal = {Mendeleev Communications},
year = {2025},
volume = {35},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {feb},
url = {https://www.mathnet.ru/mendc1387},
number = {2},
pages = {162--164},
doi = {10.71267/mencom.7616}
}
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Belyy, Alexander Yu., et al. “Electrophilic hexa(methoxycarbonyl)cycloheptatrienyl anion in the synthesis of electron-deficient 5-hydroxyisoquinolones.” Mendeleev Communications, vol. 35, no. 2, Feb. 2025, pp. 162-164. https://www.mathnet.ru/mendc1387.
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