Journal of Physical Chemistry C, volume 117, issue 14, pages 7286-7293
X-ray induced formation of metal nanoparticles from interpolyelectrolyte complexes with copper and silver ions: The radiation-chemical contrast
Publication type: Journal Article
Publication date: 2013-04-01
Journal:
Journal of Physical Chemistry C
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.7
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
Tuning the size and spatial distribution of metal nanoparticles is a key issue for obtaining metal–polymer nanocomposites with desirable properties. It was shown that the action of white X-ray radiation (bremsstrahlung, Emax ∼ 30 keV) on swollen films of interpolyelectrolyte complexes with copper and silver ions in an aqueous—alcoholic environment resulted in the formation of a specific type of metal nanostructures characterized by transmission electron microscopy (TEM). The structure pattern was explained by autocatalytic enhancement of the rate of chemical transformations in the vicinity of preformed metal nanoparticles. The effect was attributed to increasing absorption of X-ray photons by compact metal nanoparticles leading to local sensitization described as the radiation-chemical contrast. The nanostructure pattern exhibited a remarkable evolution with increasing irradiation dose. In particular, at a certain stage, the big primary nanoparticles induce formation of “clouds” of ultrasmall secondary pa...
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Feldman V. I. et al. X-ray induced formation of metal nanoparticles from interpolyelectrolyte complexes with copper and silver ions: The radiation-chemical contrast // Journal of Physical Chemistry C. 2013. Vol. 117. No. 14. pp. 7286-7293.
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Feldman V. I., Zezin A., Abramchuk S. S., Zezina E. X-ray induced formation of metal nanoparticles from interpolyelectrolyte complexes with copper and silver ions: The radiation-chemical contrast // Journal of Physical Chemistry C. 2013. Vol. 117. No. 14. pp. 7286-7293.
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TY - JOUR
DO - 10.1021/jp3090765
UR - https://doi.org/10.1021%2Fjp3090765
TI - X-ray induced formation of metal nanoparticles from interpolyelectrolyte complexes with copper and silver ions: The radiation-chemical contrast
T2 - Journal of Physical Chemistry C
AU - Feldman, Vladimir I.
AU - Zezin, A.
AU - Abramchuk, S. S.
AU - Zezina, Elena
PY - 2013
DA - 2013/04/01 00:00:00
PB - American Chemical Society (ACS)
SP - 7286-7293
IS - 14
VL - 117
SN - 1932-7447
SN - 1932-7455
ER -
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@article{2013_Feldman,
author = {Vladimir I. Feldman and A. Zezin and S. S. Abramchuk and Elena Zezina},
title = {X-ray induced formation of metal nanoparticles from interpolyelectrolyte complexes with copper and silver ions: The radiation-chemical contrast},
journal = {Journal of Physical Chemistry C},
year = {2013},
volume = {117},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Fjp3090765},
number = {14},
pages = {7286--7293},
doi = {10.1021/jp3090765}
}
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Feldman, Vladimir I., et al. “X-ray induced formation of metal nanoparticles from interpolyelectrolyte complexes with copper and silver ions: The radiation-chemical contrast.” Journal of Physical Chemistry C, vol. 117, no. 14, Apr. 2013, pp. 7286-7293. https://doi.org/10.1021%2Fjp3090765.