The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation

Zezin A.A., Feldman V.I., Zezina E.A., Belopushkin S.I., Tsybina E.V., Abramchuk S.S., Zezin S.B.
Тип документаJournal Article
Дата публикации2011-03-01
Название журналаHigh Energy Chemistry
Издатель
  • Physical and Theoretical Chemistry
Краткое описание
The features of nanoparticle formation by the radiation-chemical reduction of Cu2+ ions in polyacrylic acid-polyethyleneimine complexes have been studied. It has been shown that the swollen film/aqueous alcohol medium interphase exchange of the reducing species and the specifics of X-ray energy transfer play an important role in the formation of metal particles in the subsurface layer of polymer matrixes. An analysis of EPR and X-ray diffraction data shows that an acetaldehyde admixture increases the Cu2+ reduction rate of and enables the growth of nanoparticles.
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1. Zezin A.A. и др. The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation // High Energy Chemistry. 2011. Т. 45. № 2. С. 99–103.
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TY - JOUR

DO - 10.1134/s0018143911020147

UR - http://dx.doi.org/10.1134/S0018143911020147

TI - The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation

T2 - High Energy Chemistry

AU - Zezin, A. A.

AU - Feldman, V. I.

AU - Zezina, E. A.

AU - Belopushkin, S. I.

AU - Tsybina, E. V.

AU - Abramchuk, S. S.

AU - Zezin, S. B.

PY - 2011

DA - 2011/03

PB - Pleiades Publishing Ltd

SP - 99-103

IS - 2

VL - 45

SN - 0018-1439

SN - 1608-3148

ER -

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@article{2011,

doi = {10.1134/s0018143911020147},

url = {https://doi.org/10.1134%2Fs0018143911020147},

year = 2011,

month = {mar},

publisher = {Pleiades Publishing Ltd},

volume = {45},

number = {2},

pages = {99--103},

author = {A. A. Zezin and V. I. Feldman and E. A. Zezina and S. I. Belopushkin and E. V. Tsybina and S. S. Abramchuk and S. B. Zezin},

title = {The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper({II}) ions using X-ray irradiation}

}

MLA
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Zezin, A. A. et al. “The Formation of Metal Nanoparticles in Polyacrylic Acid-Polyethyleneimine Complex Upon Reduction of copper(II) Ions Using X-Ray Irradiation.” High Energy Chemistry 45.2 (2011): 99–103. Crossref. Web.