Journal of Organometallic Chemistry, volume 695, issue 3, pages 409-414
Bimetallic ruthenium-tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands
Therrien Bruno
1
,
Shapovalov Sergey S
,
Thai Trieu-Tien
1
,
Freudenreich Julien
1
,
Süss-Fink Georg
1
,
Pasynskii Alexandr A
2
,
Plasseraud Laurent
,
Plasseraud Laurent
3
3
Institut de Chimie Moléculaire de l’Université de Bourgogne, UMR CNRS 5260, 9 Avenue Alain Savary, Faculté des Sciences Mirande, BP 47870, 21078 Dijon Cedex, France
|
Publication type: Journal Article
Publication date: 2010-02-01
Journal:
Journal of Organometallic Chemistry
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 2.3
ISSN: 0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of neutral, anionic and cationic arene ruthenium complexes containing the trichlorostannyl ligand have been synthesised from SnCl 2 and the corresponding arene ruthenium dichloride dimers [(η 6 -arene)Ru(μ 2 -Cl)Cl] 2 (arene = C 6 H 6 , Pr i C 6 H 4 Me). While the reaction with triphenylphosphine and stannous chloride only gives the neutral mono(trichlorostannyl) complexes [(η 6 -C 6 H 6 )Ru(PPh 3 )(SnCl 3 )Cl] ( 1 ) and [(η 6 -Pr i C 6 H 4 Me)Ru(PPh 3 )(SnCl 3 )Cl] ( 2 ), the neutral di(trichlorostannyl) complex [(η 6 -Pr i C 6 H 4 Me)Ru(NCPh)(SnCl 3 ) 2 ] ( 3 ) could be obtained for the para- cymene derivative with benzonitrile as additional ligand. By contrast, the analogous reaction with the benzene derivative leads to a salt composed of the cationic mono(trichlorostannyl) complex [(η 6 -C 6 H 6 )Ru(NCPh) 2 (SnCl 3 )] + ( 5 ) and of the anionic tris(trichlorostannyl) complex [(η 6 -C 6 H 6 )Ru(SnCl 3 ) 3 ] − ( 6 ). On the other hand, [(η 6 -Pr i C 6 H 4 Me)Ru(μ 2 -Cl)Cl] 2 reacts with SnCl 2 and hexamethylenetetramine hydrochloride or 18-crown-6 to give the anionic di(trichlorostannyl) complex [(η 6 -Pr i C 6 H 4 Me)Ru(SnCl 3 ) 2 Cl] − ( 4 ), isolated as the hexamethylenetetrammonium salt or the chloro-tin 18-crown-6 salt. The single-crystal X-ray structure analyses of 1 , 2 , [(CH 2 ) 6 N 4 H][ 4 ], [(18-crown-6)SnCl][ 4 ] and [ 5 ][ 6 ] reveal for all complexes a pseudo- tetrahedral piano-stool geometry with ruthenium–tin bonds ranging from 2.56 (anionic complexes) to 2.60 A (cationic complex).
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Citations by publishers
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Therrien B. et al. Bimetallic ruthenium-tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 3. pp. 409-414.
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Therrien B., Thai T., Freudenreich J., Süss-Fink G., Shapovalov S. S., Pasynskii A. A., Plasseraud L., Shapovalov S. S., Plasseraud L. Bimetallic ruthenium-tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 3. pp. 409-414.
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TY - JOUR
DO - 10.1016/J.JORGANCHEM.2009.10.033
UR - https://doi.org/10.1016%2FJ.JORGANCHEM.2009.10.033
TI - Bimetallic ruthenium-tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands
T2 - Journal of Organometallic Chemistry
AU - Therrien, Bruno
AU - Thai, Trieu-Tien
AU - Freudenreich, Julien
AU - Süss-Fink, Georg
AU - Shapovalov, Sergey S
AU - Pasynskii, Alexandr A
AU - Plasseraud, Laurent
AU - Shapovalov, Sergey S.
AU - Plasseraud, Laurent
PY - 2010
DA - 2010/02/01 00:00:00
PB - Elsevier
SP - 409-414
IS - 3
VL - 695
SN - 0022-328X
ER -
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@article{2010_Therrien,
author = {Bruno Therrien and Trieu-Tien Thai and Julien Freudenreich and Georg Süss-Fink and Sergey S Shapovalov and Alexandr A Pasynskii and Laurent Plasseraud and Sergey S. Shapovalov and Laurent Plasseraud},
title = {Bimetallic ruthenium-tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands},
journal = {Journal of Organometallic Chemistry},
year = {2010},
volume = {695},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016%2FJ.JORGANCHEM.2009.10.033},
number = {3},
pages = {409--414},
doi = {10.1016/J.JORGANCHEM.2009.10.033}
}
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Therrien, Bruno, et al. “Bimetallic ruthenium-tin chemistry: Synthesis and molecular structure of arene ruthenium complexes containing trichlorostannyl ligands.” Journal of Organometallic Chemistry, vol. 695, no. 3, Feb. 2010, pp. 409-414. https://doi.org/10.1016%2FJ.JORGANCHEM.2009.10.033.
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