Russian Journal of Inorganic Chemistry, volume 66, issue 7, pages 975-981
Crystal Structure of Monomeric Octahedral Monooxo d 2-Rhenium(V) Complexes [ReO(Lnpenta )] with Oxygen-Containing Pentadentate-Chelate Ligands
Sergienko V S
1, 2
,
Publication type: Journal Article
Publication date: 2021-07-12
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The structural features of eleven mononuclear octahedral monooxo [d2-Re(V)] complexes $$\left[ {{\text{ReO}}\left( {{\text{L}}_{{{\text{penta}}}}^{n}} \right)} \right]$$ with pentadentate chelate ligands (3О, 2N), (2O, 3N), (2O, 2N, P), (2O, 2N, S), and (O, 2N, 2S) have been discussed. The О $$\left( {{\text{L}}_{{{\text{penta}}}}^{n}} \right)$$ atoms are always located in trans positions to multiply bonded O(oxo) ligands. It has been found that in nine compounds with negatively charged oxygen atoms of ligands $${\text{L}}_{{{\text{penta}}}}^{n}$$ in trans positions to multiply bonded O(oxo) ligands, the Re–O(L)trans bonds (1.960–2.065 Å) are comparable in length, somewhat longer or noticeably shorter than Re–O(L)cis (1.952–2.140 Å). These Re–O(L) bonds in trans positions to oxo ligands can be considered as having an increased multiplicity, since they are comparable in length (rather than elongated because of the structural manifestation of the trans-effect of the oxo ligand) with the Re–O(L)cis distances. In this case, we can speak of pseudodioxo complexes containing two ligands (O(oxo) and O(Ltrans)) with an increased order of the Re–O bonds (~2.5 and ~1.5 Å, respectively). In the other two complexes, the Re–O(Lpenta)trans bonds (2.200 and 2.252 Å) are significantly elongated. In these two cases, we should talk about the structural manifestation of the trans-effect of the multiply linked oxo ligand.
Citations by journals
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Polyhedron
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Polyhedron
1 publication, 25%
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Crystallography Reports
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Russian Journal of Inorganic Chemistry
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Russian Journal of General Chemistry
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Citations by publishers
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Pleiades Publishing
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Pleiades Publishing
2 publications, 50%
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Elsevier
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Elsevier
1 publication, 25%
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Sergienko V. S., Churakov A. Crystal Structure of Monomeric Octahedral Monooxo d 2-Rhenium(V) Complexes [ReO(Lnpenta)] with Oxygen-Containing Pentadentate-Chelate Ligands // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 7. pp. 975-981.
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Sergienko V. S., Churakov A. Crystal Structure of Monomeric Octahedral Monooxo d 2-Rhenium(V) Complexes [ReO(Lnpenta)] with Oxygen-Containing Pentadentate-Chelate Ligands // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 7. pp. 975-981.
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TY - JOUR
DO - 10.1134/S0036023621070111
UR - https://doi.org/10.1134%2FS0036023621070111
TI - Crystal Structure of Monomeric Octahedral Monooxo d 2-Rhenium(V) Complexes [ReO(Lnpenta)] with Oxygen-Containing Pentadentate-Chelate Ligands
T2 - Russian Journal of Inorganic Chemistry
AU - Churakov, A.V.
AU - Sergienko, V S
PY - 2021
DA - 2021/07/12 00:00:00
PB - Pleiades Publishing
SP - 975-981
IS - 7
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Sergienko,
author = {A.V. Churakov and V S Sergienko},
title = {Crystal Structure of Monomeric Octahedral Monooxo d 2-Rhenium(V) Complexes [ReO(Lnpenta)] with Oxygen-Containing Pentadentate-Chelate Ligands},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2FS0036023621070111},
number = {7},
pages = {975--981},
doi = {10.1134/S0036023621070111}
}
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Sergienko, V. S., et al. “Crystal Structure of Monomeric Octahedral Monooxo d 2-Rhenium(V) Complexes [ReO(Lnpenta)] with Oxygen-Containing Pentadentate-Chelate Ligands.” Russian Journal of Inorganic Chemistry, vol. 66, no. 7, Jul. 2021, pp. 975-981. https://doi.org/10.1134%2FS0036023621070111.