Dyes and Pigments, volume 195, pages 109701
Bright Yb3+ complexes for efficient pure near-infrared OLEDs
Metlin Mikhail T
1, 2
,
Kiskin Mikhail A
,
Taydakov Ilya V.
3
,
Goryachii Dmitry O
3
,
Aminev Denis F
3
,
Datskevich Nikolay P
3
,
Garaeva Veronika V
4, 5
,
Korshunov Vladislav M
,
Metlina Daria A
3
,
Mikhalchenko Lyudmila V
6
,
Pavlov Alexander
4
,
Publication type: Journal Article
Publication date: 2021-11-01
Journal:
Dyes and Pigments
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.5
ISSN: 01437208, 18733743
General Chemical Engineering
Process Chemistry and Technology
Abstract
Abstract A series of neutral Yb3+ and Gd3+ complexes with isomeric 4,4,4-trifluoro-1-(naphthalenyl)butane-1,3-diones and 1,10-phenanthroline as an ancillary ligand were synthesized and characterized by a full range of analytical methods, including elemental analysis, FTIR and NMR spectroscopy, single crystal X-ray analysis, cyclic voltammetry (CVA) and thermal analysis (TG/DTA). Moreover, the unexpected formation of a mixed diketonate-carboxylate Yb3+ complex [Yb(2-Naph)2(CF3COO)(phen)(H2O)] from [Yb(2-Naph)3(phen)] in solution was observed. The photoluminescence quantum yield (PLQY) for complex [Yb(2-Naph)3(phen)] in the near infra-red region (one band with a peak at 980 nm) was about 3,2%. This value is close to the highest one reported for 1,3-diketonate complexes of Yb3+ ion to date. The energy transfer process is discussed in details, based on the results of TD-DFT calculations and experimental photophysical measurements. These complexes were successfully used as emitters in multilayer OLEDs. The electroluminescence quantum efficiency corresponding to the sole band at 980 nm reached 0.042% with a maximum irradiance of 11 μW/cm2 at 8.5 V for [Yb(2-Naph)3(phen)] based device, which is unusually high for such type of emitters.
Citations by journals
|
1
2
3
|
|
|
Journal of Luminescence
|
Journal of Luminescence
3 publications, 18.75%
|
|
Dalton Transactions
|
Dalton Transactions
3 publications, 18.75%
|
|
Inorganics
|
Inorganics
1 publication, 6.25%
|
|
Catalysis Today
|
Catalysis Today
1 publication, 6.25%
|
|
Materials
|
Materials
1 publication, 6.25%
|
|
MolBank
|
MolBank
1 publication, 6.25%
|
|
Journal of Materials Science
|
Journal of Materials Science
1 publication, 6.25%
|
|
Journal of Materials Science: Materials in Electronics
|
Journal of Materials Science: Materials in Electronics
1 publication, 6.25%
|
|
International Journal of Molecular Sciences
|
International Journal of Molecular Sciences
1 publication, 6.25%
|
|
Journal of Applied Spectroscopy
|
Journal of Applied Spectroscopy
1 publication, 6.25%
|
|
Dyes and Pigments
|
Dyes and Pigments
1 publication, 6.25%
|
|
Molecules
|
Molecules
1 publication, 6.25%
|
|
1
2
3
|
Citations by publishers
|
1
2
3
4
5
|
|
|
Elsevier
|
Elsevier
5 publications, 31.25%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
5 publications, 31.25%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
3 publications, 18.75%
|
|
Springer Nature
|
Springer Nature
3 publications, 18.75%
|
|
1
2
3
4
5
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[8,8],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["50","50"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Luminescence","Dalton Transactions","Inorganics","Catalysis Today","Materials","MolBank","Journal of Materials Science","Journal of Materials Science: Materials in Electronics","International Journal of Molecular Sciences","Journal of Applied Spectroscopy","Dyes and Pigments","Molecules"],"ids":[7075,8473,4005,14481,25198,20017,11453,20208,14627,21731,10101,1770],"codes":[0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[3,3,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[18.75,18.75,6.25,6.25,6.25,6.25,6.25,6.25,6.25,6.25,6.25,6.25],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Multidisciplinary Digital Publishing Institute (MDPI)","Royal Society of Chemistry (RSC)","Springer Nature"],"ids":[17,202,123,8],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[5,5,3,3],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[31.25,31.25,18.75,18.75],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Metlin M. T. et al. Bright Yb3+ complexes for efficient pure near-infrared OLEDs // Dyes and Pigments. 2021. Vol. 195. p. 109701.
GOST all authors (up to 50)
Copy
Metlin M. T., Goryachii D. O., Aminev D. F., Datskevich N. P., Kiskin M. A., Garaeva V. V., Taydakov I. V., Korshunov V. M., Metlina D. A., Pavlov A. A., Mikhalchenko L. V., Korshunov V., Pavlov A., Kiskin M. A. Bright Yb3+ complexes for efficient pure near-infrared OLEDs // Dyes and Pigments. 2021. Vol. 195. p. 109701.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.dyepig.2021.109701
UR - https://doi.org/10.1016%2Fj.dyepig.2021.109701
TI - Bright Yb3+ complexes for efficient pure near-infrared OLEDs
T2 - Dyes and Pigments
AU - Metlin, Mikhail T
AU - Goryachii, Dmitry O
AU - Aminev, Denis F
AU - Datskevich, Nikolay P
AU - Kiskin, Mikhail A
AU - Garaeva, Veronika V
AU - Taydakov, Ilya V.
AU - Korshunov, Vladislav M
AU - Metlina, Daria A
AU - Pavlov, Alexander A.
AU - Mikhalchenko, Lyudmila V
AU - Korshunov, Vladislav
AU - Pavlov, Alexander
AU - Kiskin, Mikhail A.
PY - 2021
DA - 2021/11/01 00:00:00
PB - Elsevier
SP - 109701
VL - 195
SN - 0143-7208
SN - 1873-3743
ER -
Cite this
BibTex
Copy
@article{2021_Metlin,
author = {Mikhail T Metlin and Dmitry O Goryachii and Denis F Aminev and Nikolay P Datskevich and Mikhail A Kiskin and Veronika V Garaeva and Ilya V. Taydakov and Vladislav M Korshunov and Daria A Metlina and Alexander A. Pavlov and Lyudmila V Mikhalchenko and Vladislav Korshunov and Alexander Pavlov and Mikhail A. Kiskin},
title = {Bright Yb3+ complexes for efficient pure near-infrared OLEDs},
journal = {Dyes and Pigments},
year = {2021},
volume = {195},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016%2Fj.dyepig.2021.109701},
pages = {109701},
doi = {10.1016/j.dyepig.2021.109701}
}