Journal of Power Sources, volume 518, pages 230769
High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material
Buryak Nikita S
1
,
Anishchenko Dmitrii V
2, 3
,
Levin Eduard E.
2
,
Nikitina Victoria A.
2, 6
,
Antipov Evgeny V.
2, 6
Publication type: Journal Article
Publication date: 2022-01-01
Journal:
Journal of Power Sources
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.2
ISSN: 03787753
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
The recently demonstrated possibility of high-voltage extraction of more than 2 Na ions per Na 4 MnV(PO 4 ) 3 formula unit is considered as a possible way to increase the specific energy of this material, which would open up prospects for its application in sodium-ion batteries. However, for the Na 4 MnV(PO 4 ) 3 material and for a wide group of related NASICON-structured materials, high-voltage Na extraction was demonstrated to lead to a rapid decrease in capacity and a sharp increase in hysteresis between the charge and discharge curves. In this work, we use electrochemical and structural analysis to elucidate the reasons for the degradation observed after deep desodiation of Na 4 MnV(PO 4 ) 3 . X-ray diffraction analysis of the electrodes after cycling demonstrates that a phase transformation is initiated when the anodic potential limit exceeds 3.8 V, which results in the formation of distorted NASICON-type phases and gradual amorphization. X-ray absorption spectroscopy studies suggest that the observed detrimental phase transitions might be triggered by the changes in the local environment of oxidized vanadium, which destabilize the structure. We thus demonstrate that the degradation of the Na 4 MnV(PO 4 ) 3 material is of thermodynamic origin, with its consequences being reflected in a dramatically decreased de/intercalation rates and a rapid deterioration in the material performance. • High-voltage Na extraction from Na 4 MnV(PO 4 ) 3 triggers surface amorphization. • Surface changes lead to a rapid capacity fade and a continuous increase in hysteresis. • Phase transition is likely due to the instability of V +5 in the desodiated structure.
Citations by journals
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2
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Journal of Materials Chemistry A
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2 publications, 11.11%
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2 publications, 11.11%
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Small
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1 publication, 5.56%
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1
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Citations by publishers
1
2
3
4
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
4 publications, 22.22%
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
4 publications, 22.22%
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Elsevier
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Elsevier
4 publications, 22.22%
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Wiley
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Wiley
3 publications, 16.67%
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Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 11.11%
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Springer Nature
|
Springer Nature
1 publication, 5.56%
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1
2
3
4
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Buryak N. S. et al. High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material // Journal of Power Sources. 2022. Vol. 518. p. 230769.
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Buryak N. S., Anishchenko D. V., Levin E. E., Ryazantsev S. V., Martin-Diaconescu V., Zakharkin M. V., Nikitina V. A., Antipov E. V. High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material // Journal of Power Sources. 2022. Vol. 518. p. 230769.
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TY - JOUR
DO - 10.1016/j.jpowsour.2021.230769
UR - https://doi.org/10.1016%2Fj.jpowsour.2021.230769
TI - High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material
T2 - Journal of Power Sources
AU - Buryak, Nikita S
AU - Levin, Eduard E.
AU - Ryazantsev, Sergey V
AU - Martin-Diaconescu, Vlad
AU - Zakharkin, Maxim V.
AU - Nikitina, Victoria A.
AU - Antipov, Evgeny V.
AU - Anishchenko, Dmitrii V
PY - 2022
DA - 2022/01/01 00:00:00
PB - Elsevier
SP - 230769
VL - 518
SN - 0378-7753
ER -
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@article{2022_Buryak,
author = {Nikita S Buryak and Eduard E. Levin and Sergey V Ryazantsev and Vlad Martin-Diaconescu and Maxim V. Zakharkin and Victoria A. Nikitina and Evgeny V. Antipov and Dmitrii V Anishchenko},
title = {High-voltage structural evolution and its kinetic consequences for the Na4MnV(PO4)3 sodium-ion battery cathode material},
journal = {Journal of Power Sources},
year = {2022},
volume = {518},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.jpowsour.2021.230769},
pages = {230769},
doi = {10.1016/j.jpowsour.2021.230769}
}