Open Access
Polymers, volume 13, issue 22, pages 4052
Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage
Butova V.
1
,
Burachevskaya Olga A
1
,
Shepelenko Evgenii N
3
,
Tereshchenko Andrei A
1
,
Shapovalova Svetlana O
1
,
Ilin Oleg I
4
,
Bren Vladimir A.
2
,
Soldatov Alexander V.
1
Publication type: Journal Article
Publication date: 2021-11-22
PubMed ID:
34833350
General Chemistry
Polymers and Plastics
Abstract
Here, we report a new photosensitive metal–organic framework (MOF) that was constructed via the modification of UiO-66-NH2 with diarylethene molecules (DAE, 4-(5-Methoxy-1,2-dimethyl-1H-indol-3-yl)-3-(2,5-dimethylthiophen-3-yl)-4-furan-2,5-dione). The material that was obtained was a highly crystalline porous compound. The photoresponse of the modified MOF was observed via UV–Vis and IR spectroscopy. Most of the DAE molecules inside of the UiO-66-pores had an open conformation after synthesis. However, the equilibrium was able to be shifted further toward an open conformation using visible light irradiation with a wavelength of 520 nm. Conversely, UV-light with a wavelength of 450 nm initiated the transformation of the photoresponsive moieties inside of the pores to a closed modification. We have shown that this transformation could be used to stimulate hydrogen adsorption–desorption processes. Specifically, visible light irradiation increased the H2 capacity of modified MOF, while UV-light decreased it. A similar hybrid material with DAE moieties in the UiO-66 scaffold was applied for hydrogen storage for the first time. Additionally, the obtained results are promising for smart H2 storage that is able to be managed via light stimuli.
Citations by journals
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Nanomaterials
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2 publications, 14.29%
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Molecules
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1 publication, 7.14%
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Environmental Functional Materials
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1 publication, 7.14%
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1 publication, 7.14%
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Results in Physics
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1 publication, 7.14%
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Applied Organometallic Chemistry
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Applied Organometallic Chemistry
1 publication, 7.14%
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New Journal of Chemistry
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1 publication, 7.14%
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Langmuir
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Langmuir
1 publication, 7.14%
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Citations by publishers
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6
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
6 publications, 42.86%
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Elsevier
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Elsevier
4 publications, 28.57%
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Wiley
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Wiley
1 publication, 7.14%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 7.14%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 7.14%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Butova V. et al. Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage // Polymers. 2021. Vol. 13. No. 22. p. 4052.
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Butova V., Burachevskaya O. A., Podshibyakin V. A., Shepelenko E. N., Tereshchenko A. A., Shapovalova S. O., Ilin O. I., Bren V. A., Soldatov A. V. Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage // Polymers. 2021. Vol. 13. No. 22. p. 4052.
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TY - JOUR
DO - 10.3390/polym13224052
UR - https://doi.org/10.3390%2Fpolym13224052
TI - Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage
T2 - Polymers
AU - Burachevskaya, Olga A
AU - Shepelenko, Evgenii N
AU - Tereshchenko, Andrei A
AU - Shapovalova, Svetlana O
AU - Bren, Vladimir A.
AU - Soldatov, Alexander V.
AU - Butova, V.
AU - Podshibyakin, Vitaly A
AU - Ilin, Oleg I
PY - 2021
DA - 2021/11/22 00:00:00
PB - Multidisciplinary Digital Publishing Institute (MDPI)
SP - 4052
IS - 22
VL - 13
PMID - 34833350
SN - 2073-4360
ER -
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@article{2021_Butova,
author = {Olga A Burachevskaya and Evgenii N Shepelenko and Andrei A Tereshchenko and Svetlana O Shapovalova and Vladimir A. Bren and Alexander V. Soldatov and V. Butova and Vitaly A Podshibyakin and Oleg I Ilin},
title = {Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage},
journal = {Polymers},
year = {2021},
volume = {13},
publisher = {Multidisciplinary Digital Publishing Institute (MDPI)},
month = {nov},
url = {https://doi.org/10.3390%2Fpolym13224052},
number = {22},
pages = {4052},
doi = {10.3390/polym13224052}
}
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Butova, V., et al. “Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage.” Polymers, vol. 13, no. 22, Nov. 2021, p. 4052. https://doi.org/10.3390%2Fpolym13224052.