Russian Journal of Inorganic Chemistry, volume 66, issue 12, pages 1854-1859

Synthesis and Structures of Dioxomolybdenum(VI) Complexes with Hydrazones of β-Dicarbonic Compounds. Crystal Structures of Solvate Complexes МоО2L1⋅МеОН (H2L1 = Isonicotinoylhydrazone Acetylacetone) and МоО2L2 ⋅Me2SO (H2L2 = Benzoylhydrazone Benzoylacetone)

Publication typeJournal Article
Publication date2021-12-14
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Two solvate complexes МоО2L1·МеОН (H2L1 is isonicotinoyl hydrazone acetylacetone) (I) and МоО2L2·Me2SO (H2L2 is benzoylhydrazone benzoylacetone) (II) have been synthesized and their structures have been determined by X-ray diffraction. Molybdenum atoms in I and II coordinate two ligands cis-O2(oxo), N(L1,2), O(Solv) atoms in trans-positions to O(oxo), and two O(L1,2) atoms in cis-positions to O(oxo) and in trans-positions to each other to form an octahedral geometry. The average bond lengths in I and II are Mo–O(oxo) 1.698 and 1.695 Å, Mo–N(L1,2) 2.216 and 2.217 Å, Mo–O(L1,2) 1.985 and 1.969 Å, Mo–O(Solv) 2.333 and 2.316 Å, respectively. The O(oxo)MoO (oxo) bond angles are 105.7° and 105.2° in I and II, respectively.

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Sergienko V. S. et al. Synthesis and Structures of Dioxomolybdenum(VI) Complexes with Hydrazones of β-Dicarbonic Compounds. Crystal Structures of Solvate Complexes МоО2L1⋅МеОН (H2L1 = Isonicotinoylhydrazone Acetylacetone) and МоО2L2 ⋅Me2SO (H2L2 = Benzoylhydrazone Benzoylacetone) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 12. pp. 1854-1859.
GOST all authors (up to 50) Copy
Sergienko V. S., Abramenko V. L., Churakov A., Surazhskaya M. D. Synthesis and Structures of Dioxomolybdenum(VI) Complexes with Hydrazones of β-Dicarbonic Compounds. Crystal Structures of Solvate Complexes МоО2L1⋅МеОН (H2L1 = Isonicotinoylhydrazone Acetylacetone) and МоО2L2 ⋅Me2SO (H2L2 = Benzoylhydrazone Benzoylacetone) // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 12. pp. 1854-1859.
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TY - JOUR
DO - 10.1134/S0036023621120159
UR - https://doi.org/10.1134%2FS0036023621120159
TI - Synthesis and Structures of Dioxomolybdenum(VI) Complexes with Hydrazones of β-Dicarbonic Compounds. Crystal Structures of Solvate Complexes МоО2L1⋅МеОН (H2L1 = Isonicotinoylhydrazone Acetylacetone) and МоО2L2 ⋅Me2SO (H2L2 = Benzoylhydrazone Benzoylacetone)
T2 - Russian Journal of Inorganic Chemistry
AU - Churakov, A.V.
AU - Surazhskaya, M D
AU - Sergienko, V S
AU - Abramenko, V L
PY - 2021
DA - 2021/12/14 00:00:00
PB - Pleiades Publishing
SP - 1854-1859
IS - 12
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Sergienko,
author = {A.V. Churakov and M D Surazhskaya and V S Sergienko and V L Abramenko},
title = {Synthesis and Structures of Dioxomolybdenum(VI) Complexes with Hydrazones of β-Dicarbonic Compounds. Crystal Structures of Solvate Complexes МоО2L1⋅МеОН (H2L1 = Isonicotinoylhydrazone Acetylacetone) and МоО2L2 ⋅Me2SO (H2L2 = Benzoylhydrazone Benzoylacetone)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134%2FS0036023621120159},
number = {12},
pages = {1854--1859},
doi = {10.1134/S0036023621120159}
}
MLA
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Sergienko, V. S., et al. “Synthesis and Structures of Dioxomolybdenum(VI) Complexes with Hydrazones of β-Dicarbonic Compounds. Crystal Structures of Solvate Complexes МоО2L1⋅МеОН (H2L1 = Isonicotinoylhydrazone Acetylacetone) and МоО2L2 ⋅Me2SO (H2L2 = Benzoylhydrazone Benzoylacetone).” Russian Journal of Inorganic Chemistry, vol. 66, no. 12, Dec. 2021, pp. 1854-1859. https://doi.org/10.1134%2FS0036023621120159.
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