Radiation-induced radicals in different polymorphic modifications of D-mannitol: Structure, conformations and dosimetric implications

Sosulin I.S., Shiryaeva E.S., Feldman V.I.
Тип документаJournal Article
Дата публикации2015-12-27
Название журналаRadiation Physics and Chemistry
ИздательElsevier
  • Radiation
Краткое описание
Abstract The structure and conformation of radicals produced by X-ray irradiation of three polymorphic forms of d -mannitol were investigated using EPR spectroscopy. In all the cases, primary species were identified as radicals resulting from hydrogen abstraction from position 3 or 4 of the mannitol molecule. It was found that molecular packing in crystals of different polymorphic modifications had noticeable effect on the conformation of radicals observed after irradiation at room temperature and the dehydration of the primary radicals occurring at 400 K. The radicals trapped in stable modifications (β- and δ-forms) were found to be very stable at room temperature. Relatively high radical yields and remarkable stability of radicals suggest that d -mannitol can be used as an EPR dosimeter or irradiation marker.
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1. Sosulin I.S., Shiryaeva E.S., Feldman V.I. Radiation-induced radicals in different polymorphic modifications of d -mannitol: Structure, conformations and dosimetric implications // Radiation Physics and Chemistry. 2015. Т. 117. С. 178–183.
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TY - JOUR

DO - 10.1016/j.radphyschem.2015.08.011

UR - http://dx.doi.org/10.1016/J.RADPHYSCHEM.2015.08.011

TI - Radiation-induced radicals in different polymorphic modifications of d -mannitol: Structure, conformations and dosimetric implications

T2 - Radiation Physics and Chemistry

AU - Sosulin, Ilya S.

AU - Shiryaeva, Ekaterina S.

AU - Feldman, Vladimir I.

PY - 2015

DA - 2015/12

PB - Elsevier BV

SP - 178-183

VL - 117

SN - 0969-806X

ER -

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@article{2015,

doi = {10.1016/j.radphyschem.2015.08.011},

url = {https://doi.org/10.1016%2Fj.radphyschem.2015.08.011},

year = 2015,

month = {dec},

publisher = {Elsevier {BV}},

volume = {117},

pages = {178--183},

author = {Ilya S. Sosulin and Ekaterina S. Shiryaeva and Vladimir I. Feldman},

title = {Radiation-induced radicals in different polymorphic modifications of d -mannitol: Structure, conformations and dosimetric implications}

}

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Sosulin, Ilya S., Ekaterina S. Shiryaeva, and Vladimir I. Feldman. “Radiation-Induced Radicals in Different Polymorphic Modifications of d -Mannitol: Structure, Conformations and Dosimetric Implications.” Radiation Physics and Chemistry 117 (2015): 178–183. Crossref. Web.