Equimolecular cocrystal of cis- and trans-coordinated N,N′-dimethylglycolurils: Some standard thermodynamic properties in the aqueous solution between 278.15 K and 318.15 K

Ivanov E.V., Lebedeva E.Y., Batov D.V., Baranov V.V., Kravchenko A.N.
Тип документаJournal Article
Дата публикации2020-01-01
Название журналаJournal of Molecular Liquids
ИздательElsevier
КвартильQ1
ISSN01677322, 18733166
  • Materials Chemistry
  • Electronic, Optical and Magnetic Materials
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
Краткое описание
Abstract In this paper, we have discussed the results of densimetric and calorimetric studies of dissolution process in water for the (1:1) cocrystal consisting of two heterocyclic isomers being cis- and trans-coordinated dimethylglycolurils (2,8-DMGU and 2,6-DMGU, respectively) in the temperature range from (278.15 to 318.15) K at the ambient pressure. The standard (apparent or partial at infinite dilution) molar volumes and isobaric expansibilities of cocrystal as a solute in water were derived from the experimental data on solution density. Using thermochemical measurements, the standard molar enthalpies and isobaric heat capacities of the dissolution of cocrystal in water were also determined at the temperatures of interest. Based on the previously obtained similar results for aqueous 2,6-DMGU and 2,8-DMGU, a comparative analysis of packing and interaction changes in the hydration complex induced by the cocrystallization process has been carried out. It was found that the formation of cocrystal leads to a peculiar “synergism” in both volume and heat capacity effect of N,N′-dimethylglycoluril hydration at all temperatures studied.
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1. Ivanov E.V. и др. Equimolecular cocrystal of cis- and trans-coordinated N,N′-dimethylglycolurils: Some standard thermodynamic properties in the aqueous solution between 278.15 K and 318.15 K // Journal of Molecular Liquids. 2020. Т. 297. С. 111891.
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TY - JOUR

DO - 10.1016/j.molliq.2019.111891

UR - http://dx.doi.org/10.1016/j.molliq.2019.111891

TI - Equimolecular cocrystal of cis- and trans-coordinated N,N′-dimethylglycolurils: Some standard thermodynamic properties in the aqueous solution between 278.15 K and 318.15 K

T2 - Journal of Molecular Liquids

AU - Ivanov, Evgeniy V.

AU - Lebedeva, Elena Yu

AU - Batov, Dmitriy V.

AU - Baranov, Vladimir V.

AU - Kravchenko, Angelina N.

PY - 2020

DA - 2020/01

PB - Elsevier BV

SP - 111891

VL - 297

SN - 0167-7322

ER -

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@article{2020,

doi = {10.1016/j.molliq.2019.111891},

url = {https://doi.org/10.1016%2Fj.molliq.2019.111891},

year = 2020,

month = {jan},

publisher = {Elsevier {BV}},

volume = {297},

pages = {111891},

author = {Evgeniy V. Ivanov and Elena Yu Lebedeva and Dmitriy V. Batov and Vladimir V. Baranov and Angelina N. Kravchenko},

title = {Equimolecular cocrystal of cis- and trans-coordinated N,N$\prime$-dimethylglycolurils: Some standard thermodynamic properties in the aqueous solution between 278.15~K and 318.15~K}

}

MLA
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Ivanov, Evgeniy V. et al. “Equimolecular Cocrystal of Cis- and Trans-Coordinated N,N′-Dimethylglycolurils: Some Standard Thermodynamic Properties in the Aqueous Solution Between 278.15 K and 318.15 K.” Journal of Molecular Liquids 297 (2020): 111891. Crossref. Web.