Radiochimica Acta, volume 102, issue 3, pages 227-237
On existence and properties of plutonium(VIII) derivatives
Kiselev Yu M
1
,
Nikonov M.V.
2
,
Dolzhenko V D
1
,
Ermilov A.Yu.
1
,
Tananaev I. G.
3
,
Myasoedov B. F.
2
3
Institute of physical chemistry and electrochemiostry of Russian Academy of Science, Ltninsky ave. 31/4, 119071, Moscow, Russia
|
Publication type: Journal Article
Publication date: 2014-02-17
Journal:
Radiochimica Acta
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 1.8
ISSN: 00338230, 21933405
Physical and Theoretical Chemistry
Abstract
The existence of Pu(VIII) was shown in alkaline solutions and in nonpolar solvents (CCl4 and CHCl3) on the ground of such experimental facts like extraction of plutonium species, obtained by means of ozonization of Pu(VI) alkaline solutions into CCl4 and CHCl3; volatility of Pu compounds out of aqueous alkaline solutions, and the mentioned solvents. The product of interaction between PuO3 · 0.8H2O and XeF2 in CCl4 and CHCl3 was of the same chemical form for both cases and identical with the form of the product of volatility of Pu out of these organic solutions. The electronic absorbance spectra of these products in CCl4 and CHCl3 were fairly similar to the ones for OsO4 and RuO4. The band of absorption in these spectra with the maximum at 332 nm corresponds to the charge transfer of metal-ligand type [π(O)→Pu], as the value of molar extinction coefficient ε was found to be higher than 2 · 103 L/mole cm. A satisfactory agreement between the energies for the transitions of PuO4 molecule designed by X α -SW method and experimental data was observed. A similar accordance was observed for the designed vibration frequency (DFT-method) with the one found as result of analysis of the vibration structure of the experimental spectra.
Citations by journals
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Nature Chemistry
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1 publication, 20%
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Citations by publishers
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1
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Springer Nature
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Springer Nature
2 publications, 40%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 20%
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Walter de Gruyter
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Walter de Gruyter
1 publication, 20%
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1
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Kiselev Yu. M. et al. On existence and properties of plutonium(VIII) derivatives // Radiochimica Acta. 2014. Vol. 102. No. 3. pp. 227-237.
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Kiselev Yu. M., Nikonov M., Dolzhenko V. D., Ermilov A., Tananaev I. G., Myasoedov B. F. On existence and properties of plutonium(VIII) derivatives // Radiochimica Acta. 2014. Vol. 102. No. 3. pp. 227-237.
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TY - JOUR
DO - 10.1515/ract-2014-2146
UR - https://doi.org/10.1515%2Fract-2014-2146
TI - On existence and properties of plutonium(VIII) derivatives
T2 - Radiochimica Acta
AU - Kiselev, Yu M
AU - Nikonov, M.V.
AU - Dolzhenko, V D
AU - Ermilov, A.Yu.
AU - Tananaev, I. G.
AU - Myasoedov, B. F.
PY - 2014
DA - 2014/02/17 00:00:00
PB - Walter de Gruyter
SP - 227-237
IS - 3
VL - 102
SN - 0033-8230
SN - 2193-3405
ER -
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@article{2014_Kiselev,
author = {Yu M Kiselev and M.V. Nikonov and V D Dolzhenko and A.Yu. Ermilov and I. G. Tananaev and B. F. Myasoedov},
title = {On existence and properties of plutonium(VIII) derivatives},
journal = {Radiochimica Acta},
year = {2014},
volume = {102},
publisher = {Walter de Gruyter},
month = {feb},
url = {https://doi.org/10.1515%2Fract-2014-2146},
number = {3},
pages = {227--237},
doi = {10.1515/ract-2014-2146}
}
Cite this
MLA
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Kiselev, Yu. M., et al. “On existence and properties of plutonium(VIII) derivatives.” Radiochimica Acta, vol. 102, no. 3, Feb. 2014, pp. 227-237. https://doi.org/10.1515%2Fract-2014-2146.
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