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Pure and Applied Chemistry, volume 92, issue 8, pages 1367-1386

Pd(0)-catalyzed amination in the synthesis of chiral derivatives of BINAM and their evaluation as fluorescent enantioselective detectors

Publication typeJournal Article
Publication date2020-08-01
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor1.8
ISSN00334545
General Chemistry
General Chemical Engineering
Abstract

A mini-review covers recent successes in the synthesis of (S)-1,1′-binaphthyl-2,2′-diamine (BINAM) using Pd(0)-catalyzed amination reactions. As a result, versatile compounds with C2-chiral backbone were synthesized, among them are derivatives bearing additional chiral amino and fluorophore groups like dansyl amide, 7-methoxycoumarin, 6-aminoquinoline, different macrocyclic compounds with oxadiamine and polyamine linkers were obtained as well. BINAM derivatives of various structures were evaluated as fluorescent enantioselective detectors for a series of model amino alcohols. Many of them were shown to be efficient in sensing certain enantiomers of the amino alcohols by selective changes in the emission in the presence of these analytes. Small changes in the structure of the BINAM derivatives lead to serious difference in the recognition ability of the compounds under investigation.

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Averin A. D. et al. Pd(0)-catalyzed amination in the synthesis of chiral derivatives of BINAM and their evaluation as fluorescent enantioselective detectors // Pure and Applied Chemistry. 2020. Vol. 92. No. 8. pp. 1367-1386.
GOST all authors (up to 50) Copy
Averin A. D., Grigorova O. K., Malysheva A. S., Beletskaya I. P., Shaferov A. V. Pd(0)-catalyzed amination in the synthesis of chiral derivatives of BINAM and their evaluation as fluorescent enantioselective detectors // Pure and Applied Chemistry. 2020. Vol. 92. No. 8. pp. 1367-1386.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1515/pac-2020-0205
UR - https://doi.org/10.1515%2Fpac-2020-0205
TI - Pd(0)-catalyzed amination in the synthesis of chiral derivatives of BINAM and their evaluation as fluorescent enantioselective detectors
T2 - Pure and Applied Chemistry
AU - Averin, Alexei D.
AU - Grigorova, Olga K
AU - Malysheva, Anna S
AU - Beletskaya, Irina P.
AU - Shaferov, Alexander V
PY - 2020
DA - 2020/08/01 00:00:00
PB - Walter de Gruyter
SP - 1367-1386
IS - 8
VL - 92
SN - 0033-4545
ER -
BibTex |
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BibTex Copy
@article{2020_Averin,
author = {Alexei D. Averin and Olga K Grigorova and Anna S Malysheva and Irina P. Beletskaya and Alexander V Shaferov},
title = {Pd(0)-catalyzed amination in the synthesis of chiral derivatives of BINAM and their evaluation as fluorescent enantioselective detectors},
journal = {Pure and Applied Chemistry},
year = {2020},
volume = {92},
publisher = {Walter de Gruyter},
month = {aug},
url = {https://doi.org/10.1515%2Fpac-2020-0205},
number = {8},
pages = {1367--1386},
doi = {10.1515/pac-2020-0205}
}
MLA
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MLA Copy
Averin, Alexei D., et al. “Pd(0)-catalyzed amination in the synthesis of chiral derivatives of BINAM and their evaluation as fluorescent enantioselective detectors.” Pure and Applied Chemistry, vol. 92, no. 8, Aug. 2020, pp. 1367-1386. https://doi.org/10.1515%2Fpac-2020-0205.
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