High Energy Chemistry, volume 41, issue 1, pages 10-19
ESR study of the mechanism of radical formation during liquid- and solid-phase radiolyses of ethylamines
Publication type: Journal Article
Publication date: 2007-02-01
Journal:
High Energy Chemistry
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 0.7
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
The formation of radicals during the liquid-phase radiolysis of ethylamine, diethylamine, and triethylamine was studied by means of the spin trapping technique. The radicals produced in ion-molecule reactions and in the rearrangement and fragmentation reactions of the primary radical cations of the amines were identified. The structure and reactions of the primary radical cations were studied in a low-temperature CFCl3 freonic matrix in which amine radical cations were generated via charge transfer from matrix radical cations to amines during freon irradiation. The results of experiments in the liquid and solid phases are consistent with one another. The structure of neutral radicals and radical cations of the ethylamines was corroborated by quantum-chemical calculations.
Citations by journals
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1
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Journal of Chemical Physics
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Journal of Chemical Physics
1 publication, 11.11%
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Applied Catalysis B: Environmental
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Applied Catalysis B: Environmental
1 publication, 11.11%
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Applied Magnetic Resonance
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Applied Magnetic Resonance
1 publication, 11.11%
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Journal of Radiation Research and Applied Sciences
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Journal of Radiation Research and Applied Sciences
1 publication, 11.11%
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Journal of Physical Chemistry A
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Journal of Physical Chemistry A
1 publication, 11.11%
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Analytical Chemistry
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Analytical Chemistry
1 publication, 11.11%
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Analytical Methods
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Analytical Methods
1 publication, 11.11%
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High Energy Chemistry
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High Energy Chemistry
1 publication, 11.11%
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Molecules
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Molecules
1 publication, 11.11%
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1
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Citations by publishers
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1
2
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 22.22%
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American Institute of Physics (AIP)
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American Institute of Physics (AIP)
1 publication, 11.11%
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Elsevier
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Elsevier
1 publication, 11.11%
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Springer Nature
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Springer Nature
1 publication, 11.11%
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Taylor & Francis
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Taylor & Francis
1 publication, 11.11%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 11.11%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 11.11%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 11.11%
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1
2
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Belevskii V. N., Belopushkin S. I., Nuzhdin K. B. ESR study of the mechanism of radical formation during liquid- and solid-phase radiolyses of ethylamines // High Energy Chemistry. 2007. Vol. 41. No. 1. pp. 10-19.
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Belevskii V. N., Belopushkin S. I., Nuzhdin K. B. ESR study of the mechanism of radical formation during liquid- and solid-phase radiolyses of ethylamines // High Energy Chemistry. 2007. Vol. 41. No. 1. pp. 10-19.
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TY - JOUR
DO - 10.1134/S0018143907010031
UR - https://doi.org/10.1134%2FS0018143907010031
TI - ESR study of the mechanism of radical formation during liquid- and solid-phase radiolyses of ethylamines
T2 - High Energy Chemistry
AU - Belevskii, V N
AU - Belopushkin, S I
AU - Nuzhdin, K B
PY - 2007
DA - 2007/02/01 00:00:00
PB - Pleiades Publishing
SP - 10-19
IS - 1
VL - 41
SN - 0018-1439
SN - 1608-3148
ER -
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@article{2007_Belevskii,
author = {V N Belevskii and S I Belopushkin and K B Nuzhdin},
title = {ESR study of the mechanism of radical formation during liquid- and solid-phase radiolyses of ethylamines},
journal = {High Energy Chemistry},
year = {2007},
volume = {41},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134%2FS0018143907010031},
number = {1},
pages = {10--19},
doi = {10.1134/S0018143907010031}
}
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Belevskii, V. N., et al. “ESR study of the mechanism of radical formation during liquid- and solid-phase radiolyses of ethylamines.” High Energy Chemistry, vol. 41, no. 1, Feb. 2007, pp. 10-19. https://doi.org/10.1134%2FS0018143907010031.
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