Carbene-insertion noble gas compounds: FKrCF and FXeCF

Тип документаJournal Article
Дата публикации2020-04-01
Название журналаChemical Physics Letters
  • Physical and Theoretical Chemistry
  • General Physics and Astronomy
Краткое описание
Abstract FKrCF and FXeCF were synthetized in solid krypton and xenon matrices at cryogenic temperatures. These molecules representing a new class of noble-gas compounds are formed as a result of reaction between mobile F atoms and trapped CF fragment in solid Kr and Xe, which occur after X-ray radiolysis of CH2F2 in the corresponding matrices. The assignment was based on comparison with previously published computational data (Chopra et al., Chem. Phys., 2017, 494, 20) and the results of additional quantum chemical calculations. New molecules were found to be sensitive to near-IR, visible and UV light.
Пристатейные ссылки: 36
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1. Sosulin I.S., Tyurin D.A., Feldman V.I. Carbene-insertion noble gas compounds: FKrCF and FXeCF // Chemical Physics Letters. 2020. Т. 744. С. 137211.


DO - 10.1016/j.cplett.2020.137211

UR -

TI - Carbene-insertion noble gas compounds: FKrCF and FXeCF

T2 - Chemical Physics Letters

AU - Sosulin, Ilya S.

AU - Tyurin, Daniil A.

AU - Feldman, Vladimir I.

PY - 2020

DA - 2020/04

PB - Elsevier BV

SP - 137211

VL - 744

SN - 0009-2614

ER -

BibTex |


doi = {10.1016/j.cplett.2020.137211},

url = {},

year = 2020,

month = {apr},

publisher = {Elsevier {BV}},

volume = {744},

pages = {137211},

author = {Ilya S. Sosulin and Daniil A. Tyurin and Vladimir I. Feldman},

title = {Carbene-insertion noble gas compounds: {FKrCF} and {FXeCF}}


Sosulin, Ilya S., Daniil A. Tyurin, и Vladimir I. Feldman. «Carbene-insertion noble gas compounds: FKrCF and FXeCF». Chemical Physics Letters 744 (2020): 137211. Crossref. Web.