Chemical Physics Letters, volume 744, pages 137211
Carbene-insertion noble gas compounds: FKrCF and FXeCF
Publication type: Journal Article
Publication date: 2020-04-01
Journal:
Chemical Physics Letters
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor: 2.8
ISSN: 00092614
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Abstract FKrCF and FXeCF were synthetized in solid krypton and xenon matrices at cryogenic temperatures. These molecules representing a new class of noble-gas compounds are formed as a result of reaction between mobile F atoms and trapped CF fragment in solid Kr and Xe, which occur after X-ray radiolysis of CH2F2 in the corresponding matrices. The assignment was based on comparison with previously published computational data (Chopra et al., Chem. Phys., 2017, 494, 20) and the results of additional quantum chemical calculations. New molecules were found to be sensitive to near-IR, visible and UV light.
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Sosulin I. S. et al. Carbene-insertion noble gas compounds: FKrCF and FXeCF // Chemical Physics Letters. 2020. Vol. 744. p. 137211.
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Sosulin I. S., Tyurin D. A., Feldman V. I. Carbene-insertion noble gas compounds: FKrCF and FXeCF // Chemical Physics Letters. 2020. Vol. 744. p. 137211.
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TY - JOUR
DO - 10.1016/j.cplett.2020.137211
UR - https://linkinghub.elsevier.com/retrieve/pii/S0009261420301263
TI - Carbene-insertion noble gas compounds: FKrCF and FXeCF
T2 - Chemical Physics Letters
AU - Sosulin, Ilya S
AU - Tyurin, Daniil A
AU - Feldman, Vladimir I.
PY - 2020
DA - 2020/04/01
PB - Elsevier
SP - 137211
VL - 744
SN - 0009-2614
ER -
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@article{2020_Sosulin,
author = {Ilya S Sosulin and Daniil A Tyurin and Vladimir I. Feldman},
title = {Carbene-insertion noble gas compounds: FKrCF and FXeCF},
journal = {Chemical Physics Letters},
year = {2020},
volume = {744},
publisher = {Elsevier},
month = {apr},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0009261420301263},
pages = {137211},
doi = {10.1016/j.cplett.2020.137211}
}