Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”
Yannick D Bidal
1
,
Mathieu Lesieur
1
,
Mohand Melaimi
2
,
Fady Nahra
1
,
David B. Cordes
1
,
Kasun S. Athukorala Arachchige
1
,
Gilles Bertrand
2
,
Publication type: Journal Article
Publication date: 2015-10-12
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
The synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC- and triazolylidene-based copper(I) complexes.
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Metrics
74
Total citations:
74
Citations from 2024:
6
(8.11%)
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GOST
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Bidal Y. D. et al. Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry” // Advanced Synthesis and Catalysis. 2015. Vol. 357. No. 14-15. pp. 3155-3161.
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Bidal Y. D., Lesieur M., Melaimi M., Nahra F., Cordes D. B., Arachchige K. S. A., Slawin A. M. Z., Bertrand G., Cazin C. S. J. Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry” // Advanced Synthesis and Catalysis. 2015. Vol. 357. No. 14-15. pp. 3155-3161.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.201500453
UR - https://doi.org/10.1002/adsc.201500453
TI - Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”
T2 - Advanced Synthesis and Catalysis
AU - Bidal, Yannick D
AU - Lesieur, Mathieu
AU - Melaimi, Mohand
AU - Nahra, Fady
AU - Cordes, David B.
AU - Arachchige, Kasun S. Athukorala
AU - Slawin, Alexandra M. Z.
AU - Bertrand, Gilles
AU - Cazin, Catherine S. J.
PY - 2015
DA - 2015/10/12
PB - Wiley
SP - 3155-3161
IS - 14-15
VL - 357
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Bidal,
author = {Yannick D Bidal and Mathieu Lesieur and Mohand Melaimi and Fady Nahra and David B. Cordes and Kasun S. Athukorala Arachchige and Alexandra M. Z. Slawin and Gilles Bertrand and Catherine S. J. Cazin},
title = {Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”},
journal = {Advanced Synthesis and Catalysis},
year = {2015},
volume = {357},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/adsc.201500453},
number = {14-15},
pages = {3155--3161},
doi = {10.1002/adsc.201500453}
}
Cite this
MLA
Copy
Bidal, Yannick D., et al. “Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”.” Advanced Synthesis and Catalysis, vol. 357, no. 14-15, Oct. 2015, pp. 3155-3161. https://doi.org/10.1002/adsc.201500453.