Copper(I)-Catalyzed Regioselective Chan-Lam N2-Vinylation of 1,2,3-Triazoles and Tetrazoles
Publication type: Journal Article
Publication date: 2019-05-16
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
Copper‐catalyzed coupling of π‐deficient NH‐azoles with vinylboronic acids or vinyltrifluoroborate salt provides a direct route to N2‐vinyl‐1,2,3‐triazoles and N2‐vinyltetrazoles. The coupling reaction is efficiently catalyzed by (phen)Cu(PPh3)Br with low catalyst loading (5 mol%) under base‐free conditions. The method is applicable for vinylation of unsubstituted, monosubstituted, and disubstituted 1,2,3‐triazoles with various functionalities with high N2‐selectivity.
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Metrics
31
Total citations:
31
Citations from 2024:
6
(19.36%)
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GOST
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Motornov V. et al. Copper(I)-Catalyzed Regioselective Chan-Lam N2-Vinylation of 1,2,3-Triazoles and Tetrazoles // Advanced Synthesis and Catalysis. 2019. Vol. 361. No. 14. pp. 3306-3311.
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Motornov V. A., Motornov V., Latyshev G. V., Kotovshchikov Y. N., Lukashev N. V., Beletskaya I. P. Copper(I)-Catalyzed Regioselective Chan-Lam N2-Vinylation of 1,2,3-Triazoles and Tetrazoles // Advanced Synthesis and Catalysis. 2019. Vol. 361. No. 14. pp. 3306-3311.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.201900225
UR - https://onlinelibrary.wiley.com/doi/10.1002/adsc.201900225
TI - Copper(I)-Catalyzed Regioselective Chan-Lam N2-Vinylation of 1,2,3-Triazoles and Tetrazoles
T2 - Advanced Synthesis and Catalysis
AU - Motornov, Vladimir A
AU - Motornov, Vladimir
AU - Latyshev, Gennadij V
AU - Kotovshchikov, Yury N
AU - Lukashev, Nikolay V
AU - Beletskaya, Irina P.
PY - 2019
DA - 2019/05/16
PB - Wiley
SP - 3306-3311
IS - 14
VL - 361
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Motornov,
author = {Vladimir A Motornov and Vladimir Motornov and Gennadij V Latyshev and Yury N Kotovshchikov and Nikolay V Lukashev and Irina P. Beletskaya},
title = {Copper(I)-Catalyzed Regioselective Chan-Lam N2-Vinylation of 1,2,3-Triazoles and Tetrazoles},
journal = {Advanced Synthesis and Catalysis},
year = {2019},
volume = {361},
publisher = {Wiley},
month = {may},
url = {https://onlinelibrary.wiley.com/doi/10.1002/adsc.201900225},
number = {14},
pages = {3306--3311},
doi = {10.1002/adsc.201900225}
}
Cite this
MLA
Copy
Motornov, Vladimir, et al. “Copper(I)-Catalyzed Regioselective Chan-Lam N2-Vinylation of 1,2,3-Triazoles and Tetrazoles.” Advanced Synthesis and Catalysis, vol. 361, no. 14, May. 2019, pp. 3306-3311. https://onlinelibrary.wiley.com/doi/10.1002/adsc.201900225.