Advanced Synthesis and Catalysis, volume 365, issue 19, pages 3375-3381

Electrochemical Approach to Amide Bond Formation

Publication typeJournal Article
Publication date2023-08-31
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.4
ISSN16154150, 16154169
General Chemistry
Abstract

Electrochemical amidation of the C(sp2)−H and C(sp3)−H bonds of broad spectrum of arenes toward the direct synthesis of anilides and N‐benzylamides under mild conditions (room temperature, ambient pressure) in the absence of metal catalyst and external oxidizing agents using nitriles RCN (R=Me, Et) as amide source is described. This electrochemical approach features moderate to high yields, a broad scope of arenes with different functional groups and is amenable to gram scale synthesis. The key role of the hydroxyl radical as inductor generated during the oxidation of water and fixed by a spin trap in EPR experiment has been established.

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Strekalova S. et al. Electrochemical Approach to Amide Bond Formation // Advanced Synthesis and Catalysis. 2023. Vol. 365. No. 19. pp. 3375-3381.
GOST all authors (up to 50) Copy
Strekalova S., Kononov A., Morozov V., Babaeva O., Gavrilova E., Budnikova Y. Electrochemical Approach to Amide Bond Formation // Advanced Synthesis and Catalysis. 2023. Vol. 365. No. 19. pp. 3375-3381.
RIS |
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TY - JOUR
DO - 10.1002/adsc.202300736
UR - https://doi.org/10.1002%2Fadsc.202300736
TI - Electrochemical Approach to Amide Bond Formation
T2 - Advanced Synthesis and Catalysis
AU - Strekalova, Sofia
AU - Kononov, Alexander
AU - Morozov, Vladimir
AU - Babaeva, Olga
AU - Gavrilova, Elena
AU - Budnikova, Yulia
PY - 2023
DA - 2023/08/31 00:00:00
PB - Wiley
SP - 3375-3381
IS - 19
VL - 365
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
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BibTex Copy
@article{2023_Strekalova,
author = {Sofia Strekalova and Alexander Kononov and Vladimir Morozov and Olga Babaeva and Elena Gavrilova and Yulia Budnikova},
title = {Electrochemical Approach to Amide Bond Formation},
journal = {Advanced Synthesis and Catalysis},
year = {2023},
volume = {365},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002%2Fadsc.202300736},
number = {19},
pages = {3375--3381},
doi = {10.1002/adsc.202300736}
}
MLA
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MLA Copy
Strekalova, Sofia, et al. “Electrochemical Approach to Amide Bond Formation.” Advanced Synthesis and Catalysis, vol. 365, no. 19, Aug. 2023, pp. 3375-3381. https://doi.org/10.1002%2Fadsc.202300736.
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