том 28 , издание 5 , страницы 587-588

Stereocontrolled Total Synthesis of (5S,6R)-, (5S,6S)-, (5R,6R)-, and (5R,6S)(7E,9E,11Z,14Z)-5,6-Dihydroxy-7,9,11,14-icosatetraenoic Acid (5,6-DiHETE) Methyl Esters

K C Nicolaou ¹

J Y Ramphal ¹

J M Palazòn ¹

Rolando A. Spanevello ¹

Скрыть аффилиации авторов Показать аффилиации авторов: 1 аффилиация

University of Pennsylvania, Department of Chemistry, Philadelphia, PA 19104‐6323 (USA) |

Тип публикации: Journal Article

Дата публикации: 1989-05-01

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DOI: 10.1002/anie.198905871

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General Chemistry

Catalysis

Краткое описание

The (5S, 6R)-configurated title compound 1 is of interest as a biologically active metabolite of arachidonic acid. A method for the synthesis of 1 which also can be extended to the enantiomer and the two diastereomers now makes these compounds readily accessible in amounts satisfactory enough for biological experiments.

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