volume 36, issue 10, pages 1101-1103

Template-Directed Ring-Closing Metathesis: Synthesis and Polymerization of Unsaturated Crown Ether Analogs†

Michael J. Marsella ¹

Heather D. Maynard ¹

Robert K. Grubbs ¹

Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125 (USA), Fax: Int. code (818) 564‐9297, e‐mail: rhg@cco.caltech.edu |

Publication type: Journal Article

Publication date: 1997-05-15

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DOI: 10.1002/anie.199711011

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General Chemistry

Catalysis

Abstract

A highly efficient combination: template directing and olefin metathesis. The polyether dienes 1 react in good yields to give crown ethers 2 in the presence of LiClO4 and the Ru catalyst 3 (Cy = cyclohexyl). Ring-opening metathesis polymerization (ROMP) of the cyclic olefins 2 results in polymers that are capable of regenerating 2 by template-directed methathesis depolymerization.

Found

	2 4 6 8 10 12
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	2 4 6 8 10 12

	10 20 30 40 50
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	10 20 30 40 50

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