Highly Active Catalysts in Alkene Metathesis: First Observed Transformation of Allenylidene into Indenylidene via Alkenylcarbyne—Ruthenium Species
Publication type: Journal Article
Publication date: 2003-09-25
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
14520756
General Chemistry
Catalysis
Abstract
A cat. for all seasons: The transformation of the allenylidene-ruthenium complexes [RuCl(η6-arene)(CCCR2)(PR)][CF3SO3] into indenylidene species [RuCl(η6-arene)(indenylidene)(PR)][CF3SO3]2 by the simple protonation with CF3SO3H and formation of an alkenylcarbyne intermediate (see picture; arene=p-cymene) is observed by low temperature NMR experiments. The new in situ generated 18 electron ionic indenylidene species are highly active in the polymerization of cyclooctene and cyclopentene, ring-closing metathesis of dienes and enynes, and the acyclic diene metathesis of decadiene, thus making it a catalyst for all seasons.
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Total citations:
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Citations from 2024:
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Castarlenas R., Dixneuf P. H. Highly Active Catalysts in Alkene Metathesis: First Observed Transformation of Allenylidene into Indenylidene via Alkenylcarbyne—Ruthenium Species // Angewandte Chemie - International Edition. 2003. Vol. 42. No. 37. pp. 4524-4527.
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Castarlenas R., Dixneuf P. H. Highly Active Catalysts in Alkene Metathesis: First Observed Transformation of Allenylidene into Indenylidene via Alkenylcarbyne—Ruthenium Species // Angewandte Chemie - International Edition. 2003. Vol. 42. No. 37. pp. 4524-4527.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.200352108
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.200352108
TI - Highly Active Catalysts in Alkene Metathesis: First Observed Transformation of Allenylidene into Indenylidene via Alkenylcarbyne—Ruthenium Species
T2 - Angewandte Chemie - International Edition
AU - Castarlenas, R.
AU - Dixneuf, Pierre H.
PY - 2003
DA - 2003/09/25
PB - Wiley
SP - 4524-4527
IS - 37
VL - 42
PMID - 14520756
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Castarlenas,
author = {R. Castarlenas and Pierre H. Dixneuf},
title = {Highly Active Catalysts in Alkene Metathesis: First Observed Transformation of Allenylidene into Indenylidene via Alkenylcarbyne—Ruthenium Species},
journal = {Angewandte Chemie - International Edition},
year = {2003},
volume = {42},
publisher = {Wiley},
month = {sep},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.200352108},
number = {37},
pages = {4524--4527},
doi = {10.1002/anie.200352108}
}
Cite this
MLA
Copy
Castarlenas, R., and Pierre H. Dixneuf. “Highly Active Catalysts in Alkene Metathesis: First Observed Transformation of Allenylidene into Indenylidene via Alkenylcarbyne—Ruthenium Species.” Angewandte Chemie - International Edition, vol. 42, no. 37, Sep. 2003, pp. 4524-4527. https://onlinelibrary.wiley.com/doi/10.1002/anie.200352108.