Angewandte Chemie - International Edition, volume 42, issue 44, pages 5487-5489
Iron-Catalyzed Asymmetric Sulfide Oxidation with Aqueous Hydrogen Peroxide
Isabelle Beurton Chataigner
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Publication type: Journal Article
Publication date: 2003-11-17
scimago Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
PubMed ID:
14618584
General Chemistry
Catalysis
Abstract
An iron in the fire: Iron-based catalysts promote the asymmetric oxidation of alkyl aryl sulfides to the corresponding sulfoxides with up to 90 % ee (see scheme). Simple hydrogen peroxide (30 % in water) serves as the terminal oxidant.
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