Angewandte Chemie - International Edition, volume 42, issue 44, pages 5487-5489

Iron-Catalyzed Asymmetric Sulfide Oxidation with Aqueous Hydrogen Peroxide

Publication typeJournal Article
Publication date2003-11-17
scimago Q1
SJR5.300
CiteScore26.6
Impact factor16.1
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
An iron in the fire: Iron-based catalysts promote the asymmetric oxidation of alkyl aryl sulfides to the corresponding sulfoxides with up to 90 % ee (see scheme). Simple hydrogen peroxide (30 % in water) serves as the terminal oxidant.
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