Angewandte Chemie - International Edition, volume 43, issue 48, pages 6618-6639

Discrete Metal-Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism

Publication typeJournal Article
Publication date2004-12-10
scimago Q1
SJR5.300
CiteScore26.6
Impact factor16.1
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
Given the non-renewable nature of synthetic polymers from petroleum feedstocks, there is increasing interest in developing routes to biodegradable polymeric materials from renewable resources. Polycarbonates made from CO2 and epoxides (see scheme) have the potential to meet these important goals. Reviewed here are well-defined catalysts for epoxide–CO2 copolymerization and related reactions.
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