Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO)
Michael S Klenov
1
,
Alexey A Guskov
1
,
Oleg V Anikin
1
,
Yurii A. Strelenko
1
,
Ivan V. Fedyanin
2
,
Vladimir A Tartakovsky
1
Publication type: Journal Article
Publication date: 2016-07-20
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
27435378
General Chemistry
Catalysis
Abstract
This study presents the first synthesis and characterization of a new high energy compound [1,2,3,4]tetrazino[5,6-e][1,2,3,4]tetrazine 1,3,6,8-tetraoxide (TTTO). It was synthesized in ten steps from 2,2-bis(tert-butyl-NNO-azoxy)acetonitrile. The synthetic strategy was based on the sequential closure of two 1,2,3,4-tetrazine 1,3-dioxide rings by the generation of oxodiazonium ions and their intramolecular coupling with tert-butyl-NNO-azoxy groups. The TTTO structure was confirmed by single-crystal X-ray.
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143
Total citations:
143
Citations from 2024:
22
(15%)
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GOST
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Klenov M. S. et al. Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO) // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 38. pp. 11472-11475.
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Klenov M. S., Guskov A. A., Anikin O. V., Churakov A. M., Strelenko Y. A., Fedyanin I. V., Lyssenko K. A., Tartakovsky V. A. Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO) // Angewandte Chemie - International Edition. 2016. Vol. 55. No. 38. pp. 11472-11475.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201605611
UR - https://doi.org/10.1002/anie.201605611
TI - Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO)
T2 - Angewandte Chemie - International Edition
AU - Klenov, Michael S
AU - Guskov, Alexey A
AU - Anikin, Oleg V
AU - Churakov, Aleksandr M
AU - Strelenko, Yurii A.
AU - Fedyanin, Ivan V.
AU - Lyssenko, Konstantin A.
AU - Tartakovsky, Vladimir A
PY - 2016
DA - 2016/07/20
PB - Wiley
SP - 11472-11475
IS - 38
VL - 55
PMID - 27435378
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Klenov,
author = {Michael S Klenov and Alexey A Guskov and Oleg V Anikin and Aleksandr M Churakov and Yurii A. Strelenko and Ivan V. Fedyanin and Konstantin A. Lyssenko and Vladimir A Tartakovsky},
title = {Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO)},
journal = {Angewandte Chemie - International Edition},
year = {2016},
volume = {55},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/anie.201605611},
number = {38},
pages = {11472--11475},
doi = {10.1002/anie.201605611}
}
Cite this
MLA
Copy
Klenov, Michael S., et al. “Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO).” Angewandte Chemie - International Edition, vol. 55, no. 38, Jul. 2016, pp. 11472-11475. https://doi.org/10.1002/anie.201605611.