Angewandte Chemie - International Edition, volume 56, issue 16, pages 4512-4514
A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion
Publication type: Journal Article
Publication date: 2017-03-22
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
The reactions of (N5 )6 (H3 O)3 (NH4 )4 Cl with Co(NO3 )2 ⋅6 H2 O at room temperature yielded Co(N5 )2 (H2 O)4 ⋅4 H2 O as an air-stable orange metal complex. The structure, as determined by single-crystal X-ray diffraction, has two planar cyclo-N5- rings and four bound water molecules symmetrically positioned around the central metal ion. Thermal analysis demonstrated the explosive properties of the material.
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Zhang C. et al. A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 16. pp. 4512-4514.
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Zhang C., Yang C., Hu B., Yu C., Zheng Z., Sun C. A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 16. pp. 4512-4514.
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TY - JOUR
DO - 10.1002/anie.201701070
UR - https://doi.org/10.1002/anie.201701070
TI - A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion
T2 - Angewandte Chemie - International Edition
AU - Zhang, Chong
AU - Yang, Chen
AU - Hu, Bingcheng
AU - Yu, Chuanming
AU - Zheng, Zhansheng
AU - Sun, Chengguo
PY - 2017
DA - 2017/03/22
PB - Wiley
SP - 4512-4514
IS - 16
VL - 56
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2017_Zhang,
author = {Chong Zhang and Chen Yang and Bingcheng Hu and Chuanming Yu and Zhansheng Zheng and Chengguo Sun},
title = {A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion},
journal = {Angewandte Chemie - International Edition},
year = {2017},
volume = {56},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.201701070},
number = {16},
pages = {4512--4514},
doi = {10.1002/anie.201701070}
}
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Zhang, Chong, et al. “A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion.” Angewandte Chemie - International Edition, vol. 56, no. 16, Mar. 2017, pp. 4512-4514. https://doi.org/10.1002/anie.201701070.