Angewandte Chemie - International Edition, volume 56, issue 16, pages 4512-4514
A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion
Chong Zhang
1
,
Chen Yang
1
,
Bingcheng Hu
1
,
Chuanming Yu
1
,
Zhansheng Zheng
1
,
Chengguo Sun
2
Publication type: Journal Article
Publication date: 2017-03-22
scimago Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
PubMed ID:
28328154
General Chemistry
Catalysis
Abstract
The reactions of (N5 )6 (H3 O)3 (NH4 )4 Cl with Co(NO3 )2 ⋅6 H2 O at room temperature yielded Co(N5 )2 (H2 O)4 ⋅4 H2 O as an air-stable orange metal complex. The structure, as determined by single-crystal X-ray diffraction, has two planar cyclo-N5- rings and four bound water molecules symmetrically positioned around the central metal ion. Thermal analysis demonstrated the explosive properties of the material.
Found
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