Direct Solar‐to‐Electrochemical Energy Storage in a Functionalized Covalent Organic Framework
Тип публикации: Journal Article
Дата публикации: 2018-09-03
SCImago Q1
Tоп 10% SCImago
БС1
SJR: 5.495
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30094899
General Chemistry
Catalysis
Краткое описание
A covalent organic framework integrating naphthalenediimide and triphenylamine units (NT‐COF) is presented. Two‐dimensional porous nanosheets are packed with a high specific surface area of 1276 m2 g−1. Photo/electrochemical measurements reveal the ultrahigh efficient intramolecular charge transfer from the TPA to the NDI and the highly reversible electrochemical reaction in NT‐COF. There is a synergetic effect in NT‐COF between the reversible electrochemical reaction and intramolecular charge transfer with enhanced solar energy efficiency and an accelerated electrochemical reaction. This synergetic mechanism provides the key basis for direct solar‐to‐electrochemical energy conversion/storage. With the NT‐COF as the cathode materials, a solar Li‐ion battery is realized with decreased charge voltage (by 0.5 V), increased discharge voltage (by 0.5 V), and extra 38.7 % battery efficiency.
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ГОСТ
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Lv J. et al. Direct Solar‐to‐Electrochemical Energy Storage in a Functionalized Covalent Organic Framework // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 39. pp. 12716-12720.
ГОСТ со всеми авторами (до 50)
Скопировать
Lv J., Tan Y. X., Xie J., Yang R., Muxin Yu., Sun S., Li M., Yuan D., Wang Y. Direct Solar‐to‐Electrochemical Energy Storage in a Functionalized Covalent Organic Framework // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 39. pp. 12716-12720.
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RIS
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TY - JOUR
DO - 10.1002/anie.201806596
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201806596
TI - Direct Solar‐to‐Electrochemical Energy Storage in a Functionalized Covalent Organic Framework
T2 - Angewandte Chemie - International Edition
AU - Lv, Jiangquan
AU - Tan, Yan Xi
AU - Xie, Jiafang
AU - Yang, Rui
AU - Muxin, Yu
AU - Sun, Shanshan
AU - Li, Ming-De
AU - Yuan, Daqiang
AU - Wang, Yaobing
PY - 2018
DA - 2018/09/03
PB - Wiley
SP - 12716-12720
IS - 39
VL - 57
PMID - 30094899
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2018_Lv,
author = {Jiangquan Lv and Yan Xi Tan and Jiafang Xie and Rui Yang and Yu Muxin and Shanshan Sun and Ming-De Li and Daqiang Yuan and Yaobing Wang},
title = {Direct Solar‐to‐Electrochemical Energy Storage in a Functionalized Covalent Organic Framework},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {sep},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201806596},
number = {39},
pages = {12716--12720},
doi = {10.1002/anie.201806596}
}
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MLA
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Lv, Jiangquan, et al. “Direct Solar‐to‐Electrochemical Energy Storage in a Functionalized Covalent Organic Framework.” Angewandte Chemie - International Edition, vol. 57, no. 39, Sep. 2018, pp. 12716-12720. https://onlinelibrary.wiley.com/doi/10.1002/anie.201806596.
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