Silver‐Promoted Oxidative Benzylic C−H Trifluoromethoxylation
1
Publication type: Journal Article
Publication date: 2018-09-04
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30085396
General Chemistry
Catalysis
Abstract
A silver-promoted oxidative benzylic C-H trifluoromethoxylation has been reported for the first time. With trifluoromethyl arylsulfonate as the trifluoromethoxylation reagent, various arenes, having diverse functional groups, undergo trifluoromethoxylation of their benzylic C-H bonds to form trifluoromethyl ethers under mild reaction conditions. In addition, the trifluoromethoxylation and the fluorination of methyl groups of electron-rich arenes have been achieved to prepare α-fluorobenzyl trifluoromethyl ethers in one step.
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60
Total citations:
60
Citations from 2024:
16
(27.11%)
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MLA
Cite this
GOST
Copy
Yang H. et al. Silver‐Promoted Oxidative Benzylic C−H Trifluoromethoxylation // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 40. pp. 13266-13270.
GOST all authors (up to 50)
Copy
Yang H., Wang F., Jiang X., Zhou Yu., Xu X., Tang P. Silver‐Promoted Oxidative Benzylic C−H Trifluoromethoxylation // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 40. pp. 13266-13270.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201807144
UR - https://doi.org/10.1002/anie.201807144
TI - Silver‐Promoted Oxidative Benzylic C−H Trifluoromethoxylation
T2 - Angewandte Chemie - International Edition
AU - Yang, Haodong
AU - Wang, Feng
AU - Jiang, Xiaohuan
AU - Zhou, Yu
AU - Xu, Xiufang
AU - Tang, Pingping
PY - 2018
DA - 2018/09/04
PB - Wiley
SP - 13266-13270
IS - 40
VL - 57
PMID - 30085396
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Yang,
author = {Haodong Yang and Feng Wang and Xiaohuan Jiang and Yu Zhou and Xiufang Xu and Pingping Tang},
title = {Silver‐Promoted Oxidative Benzylic C−H Trifluoromethoxylation},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/anie.201807144},
number = {40},
pages = {13266--13270},
doi = {10.1002/anie.201807144}
}
Cite this
MLA
Copy
Yang, Haodong, et al. “Silver‐Promoted Oxidative Benzylic C−H Trifluoromethoxylation.” Angewandte Chemie - International Edition, vol. 57, no. 40, Sep. 2018, pp. 13266-13270. https://doi.org/10.1002/anie.201807144.