Switch Catalysis To Deliver Multi‐Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride
Publication type: Journal Article
Publication date: 2018-12-17
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
30370965
General Chemistry
Catalysis
Abstract
Switchable polymerisation catalysis enables block polymer sequence selectivity from monomer mixtures, resulting in the formation of multiblock polyesters. The aluminium salphen catalyst switches between two different polymerisation mechanisms and selectively enchains mixtures of commercially available monomers: lactide, phthalic anhydride, and propene oxide. Sequential monomer mixture additions yield multi-block polyesters featuring 3, 7, 11, 15, 19, 23, and 27 blocks. The unparalleled catalytic selectivity can be used to access completely new multi-block polyesters relevant for future applications.
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GOST
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Stößer T., Mulryan D., Williams C. Switch Catalysis To Deliver Multi‐Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 51. pp. 16893-16897.
GOST all authors (up to 50)
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Stößer T., Mulryan D., Williams C. Switch Catalysis To Deliver Multi‐Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride // Angewandte Chemie - International Edition. 2018. Vol. 57. No. 51. pp. 16893-16897.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.201810245
UR - https://doi.org/10.1002/anie.201810245
TI - Switch Catalysis To Deliver Multi‐Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride
T2 - Angewandte Chemie - International Edition
AU - Stößer, Tim
AU - Mulryan, Daniel
AU - Williams, Charlotte
PY - 2018
DA - 2018/12/17
PB - Wiley
SP - 16893-16897
IS - 51
VL - 57
PMID - 30370965
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Stößer,
author = {Tim Stößer and Daniel Mulryan and Charlotte Williams},
title = {Switch Catalysis To Deliver Multi‐Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride},
journal = {Angewandte Chemie - International Edition},
year = {2018},
volume = {57},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/anie.201810245},
number = {51},
pages = {16893--16897},
doi = {10.1002/anie.201810245}
}
Cite this
MLA
Copy
Stößer, Tim, et al. “Switch Catalysis To Deliver Multi‐Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride.” Angewandte Chemie - International Edition, vol. 57, no. 51, Dec. 2018, pp. 16893-16897. https://doi.org/10.1002/anie.201810245.